Heterocyclic synthesis using nitrilimines: Part 3(1). Synthesis of substituted 1,2,4,5-tetrazines and 1,2,4,5-tetraaza-2-pentenes.

被引：0
|
作者：
Dalloul, HM [1 ]
Boyle, PH [1 ]
机构：
[1] Trinity Coll Dublin, Dept Chem, Dublin 2, Ireland
来源：
HETEROCYCLIC COMMUNICATIONS | 2003年 / 9卷 / 05期
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中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The reaction of nitrilimines 2a,b with hydrazones of aliphatic ketones 3 (RHNN==(CRR2)-R-1) led to the formation of the cyclocondensation products 1,2,4,5-tetrazines 4a-g when R = CH3, and to acyclic electrophilic addition products 5a-g when R = H, rather than the cyclocondensation tetrazines products 8.
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页码：507 / 514
页数：8
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