Growth, THz properties, and Hirshfeld surface studies of 4-N,N-dimethylamino-4-N-methyl-stilbazolium 2,4,6-trimethylbenzenesulfonate single crystal

被引:7
|
作者
Wang, Tianhua [1 ,2 ,3 ]
Xu, Kai [1 ,2 ,3 ]
Wang, Guanjun [1 ,2 ,3 ]
Wang, Qibo [1 ,2 ,3 ]
Chen, Rui [1 ,2 ,3 ]
Ma, Jinkang [1 ,2 ,3 ]
Cao, Lifeng [1 ,2 ,3 ]
Teng, Bing [1 ,2 ,3 ]
机构
[1] Qingdao Univ, Univ Ind Joint Ctr Ocean Observat & Broadband Com, Coll Phys, Qingdao 266071, Peoples R China
[2] Qingdao Univ, Natl Demonstrat Ctr Expt Appl Phys Educ, Qingdao 266071, Peoples R China
[3] Shandong Prov Univ Key Lab Optoelect Mat Phys & D, Qingdao 266071, Peoples R China
基金
中国国家自然科学基金;
关键词
TERAHERTZ PULSES; GENERATION; DAST;
D O I
10.1007/s10854-021-07658-9
中图分类号
TM [电工技术]; TN [电子技术、通信技术];
学科分类号
0808 ; 0809 ;
摘要
In this paper, the growth of 4-N,N-dimethylamino-4-N-methyl-stilbazolium 2,4,6-trimethylbenzenesulfonate (DSTMS), synchrotron radiation, Hirshfeld analysis, refraction and absorption in terahertz range, and THz wave generation are reported. The internal defects of DSTMS crystal are mainly dislocations by synchrotron radiation analysis. The absorption index and refractive index of THz source in the frequency range of 1 to 4 THz are studied by the difference frequency method. The generation of terahertz wave in DSTMS crystals with different thicknesses is studied. It is found that the highest terahertz conversion efficiency is 1.71 x 10(-5). In addition, the calculation and analysis of 3-D Hirshfeld surface and 2-D fingerprint of DSTMS are helpful to study the types and contribution ratios of intermolecular interactions.
引用
收藏
页码:4704 / 4711
页数:8
相关论文
共 50 条
  • [41] Physicochemical and DFT studies of organic NLO single crystal 4-methoxy-N-(2-methyl-5-nitrophenyl) benzamide
    Prabukanthan, P.
    Bhakyajothi, V
    Kumar, M. Saravana
    Dinakaran, K.
    MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 2023, 754 (01) : 43 - 67
  • [42] Growth and characterization of novel organic 3-Hydroxy Benzaldehyde-N-methyl 4 Stilbazolium Tosylate crystals for NLO applications
    Jagannathan, K.
    Umarani, P.
    Ratchagar, V.
    Ramesh, V.
    Kalainathan, S.
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 2016, 153 : 735 - 740
  • [43] Low temperature emission spectra of optically nonlinear N-benzyl-2-methyl-4-nitroaniline crystal
    Piela, Katarzyna
    Kozankiewicz, Boleslaw
    Lipinski, Jozef
    Szostak, M. Magdalena
    CHEMICAL PHYSICS, 2012, 404 : 28 - 32
  • [44] Bulk crystal growth, crystalline perfection and optical homogeneities of 2AP4N single crystals for second and third order frequency conversion and terahertz (THz) device applications
    Karuppasamy, P.
    Kamalesh, T.
    Pandian, Muthu Senthil
    Ramasamy, P.
    Sunil, Verma
    Chaudhary, A. K.
    OPTICAL MATERIALS, 2021, 118
  • [45] Characterization of all second-order nonlinear-optical coefficients of organic N-benzyl-2-methyl-4-nitroaniline crystal
    Notake, Takashi
    Takeda, Masahiro
    Okada, Shuji
    Hosobata, Takuya
    Yamagata, Yutaka
    Minamide, Hiroaki
    SCIENTIFIC REPORTS, 2019, 9 (1)
  • [46] Preparation and characterization of N-benzyl-2-methyl-4-nitroaniline (BNA) single crystals by physical vapour transport (PVT) technique
    Mythili, A.
    Srinivasan, K.
    JOURNAL OF MOLECULAR STRUCTURE, 2023, 1286
  • [47] Synthesis, growth, crystal structure and characterization of new stilbazolium derivative single crystal: (E)-4-(3-ethoxy-2-hydroxystyryl)-1-methyl pyridinium iodide (3ETSI)
    Nivetha, K.
    Madhuri, W.
    Kalainathan, S.
    JOURNAL OF MATERIALS SCIENCE-MATERIALS IN ELECTRONICS, 2017, 28 (12) : 8937 - 8949
  • [48] Synthesis, structure and electrochemical properties of a cobalt(II) complex supported by 2-tetrahydrofurfurylamino-N,N-bis(2-methylene-4-tert-butyl-6-methyl)phenol
    Lin, Chen-Neng
    Zhou, Ling-Ling
    Fu, Ling-Zhi
    Zhan, Shu-Zhong
    Chen, Cai-Hong
    INORGANIC CHEMISTRY COMMUNICATIONS, 2015, 61 : 97 - 99
  • [49] Acetonitrile vapour inclusion in single-crystal adsorbents [MII2(bza)4(pyz)]n (MII = Rh, Cu)
    Takamizawa, Satoshi
    Miyake, Ryosuke
    CRYSTENGCOMM, 2010, 12 (10): : 2728 - 2733
  • [50] Photocatalytic H2 evolution and CO2 reduction over phosphorus-doped g-C3N4 nanostructures: Electronic, Optical, and Surface properties
    Mahvelati-Shamsabadi, Tahereh
    Lee, Byeong-Kyu
    RENEWABLE & SUSTAINABLE ENERGY REVIEWS, 2020, 130