Rhodium-Catalyzed Selective C-H Bond Functionalization of Quinolines

被引：39
作者：
Dhiman, Ankit K. [1 ,2 ]
Thakur, Ankita [1 ,2 ]
Kumar, Rakesh [1 ,2 ]
Sharma, Upendra [1 ,2 ]
机构：
[1] CSIR Inst Himalayan Bioresource Technol, Chem Technol Div, Palampur, Himachal Prades, India
[2] CSIR Inst Himalayan Bioresource Technol, AcSIR, Palampur, Himachal Prades, India
来源：
ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2020年 / 9卷 / 10期
关键词：
rhodium; quinolineN-oxide; transition metal catalysis; C-H activation; RH(I)-CATALYZED DIRECT ARYLATION; N-OXIDES; C(SP(3))-H BONDS; C-8; POSITION; ACTIVATION; 8-METHYLQUINOLINES; ALKYLATION; SITE; AMIDATION; ACYLATION;
D O I：
10.1002/ajoc.202000341
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
In the last two decades, rhodium-based catalysts have been used extensively for the sp(2)and sp(3)C-H bond activation/functionalization of various arenes, heteroarenes, and aliphatic compounds, respectively. For quinoline functionalization rhodium has been used significantly as compared to other transition metals such as cobalt, copper, ruthenium, palladium and iridium. In this Minireview the progress on rhodium-catalyzed selective functionalization of quinolineN-oxides and 8-methylquinolinesviasp(2)and sp(3)C-H bond activation, respectively have been highlighted. The main focus is on reaction mechanism, substrate scope, and positional selectivity.
引用
收藏
页码：1502 / 1518
页数：17
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