Facile preparation of BiOCl/Ti3C2 hybrid photocatalyst with enhanced visible-light photocatalytic activity

被引:25
作者
Lian, Weiwei [1 ]
Wang, Libo [1 ]
Wang, Xiaolong [1 ]
Shen, Changjie [1 ]
Zhou, Aiguo [1 ]
Hu, Qianku [1 ]
机构
[1] Henan Polytech Univ, Sch Mat Sci & Engn, Jiaozuo 454000, Henan, Peoples R China
基金
中国国家自然科学基金;
关键词
Ti3C2; BiOCl; nanocomposite; semiconductors; photocatalytic; 2-DIMENSIONAL TITANIUM CARBIDE; BIOX X; MXENE; NANOCOMPOSITES; ADSORPTION; ELECTRODES; BR; CL;
D O I
10.1142/S179360471850100X
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In the present work, a novel BiOCl/Ti3C2 nanostructured composite was synthesized using a simple precipitation method. The morphology and structure of the nanocomposite were characterized while its photocatalytic properties were studied using methyl orange dye (MO) as the model pollutant under visible-light irradiation. The results indicated that the obtained BiOCl has flower-like nanostructured morphology, which is composed of nanosheets. After the introduction of Ti3C2, the petaloid-shaped BiOCl grew on the surface layers of Ti3C2. Additionally, the photocatalytic degradation tests of MO showed that the BiOCl/Ti3C2 nanocomposite had a much higher degradation efficiency compared to that of the pristine BiOCl. Herein, a possible photocatalytic mechanism for BiOCl/Ti3C2 nanocomposites was also proposed. The results suggest that the Ti3C2 addition can effectively promote the photoelectron separation from vacancies, which leads to photocatalytic activity enhancement of the BiOCl/Ti3C2 composite.
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页数:4
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共 35 条
[1]   2D metal carbides and nitrides (MXenes) for energy storage [J].
Anasori, Babak ;
Lukatskaya, Maria R. ;
Gogotsi, Yury .
NATURE REVIEWS MATERIALS, 2017, 2 (02)
[2]   A novel network porous microspheric ZnS/ZnO with enhanced visible light photocatalytic property [J].
Bai, Mingjun ;
Liu, Xiaowen .
FUNCTIONAL MATERIALS LETTERS, 2017, 10 (05)
[3]   Novel Bi2S3-sensitized BiOCl with highly visible light photocatalytic activity for the removal of rhodamine B [J].
Cao, Jing ;
Xu, Benyan ;
Lin, Haili ;
Luo, Bangde ;
Chen, Shifu .
CATALYSIS COMMUNICATIONS, 2012, 26 :204-208
[4]   Hierarchical Structures Based on Two-Dimensional Nanomaterials for Rechargeable Lithium Batteries [J].
Cong, Lina ;
Xie, Haiming ;
Li, Jinghong .
ADVANCED ENERGY MATERIALS, 2017, 7 (12)
[5]   From bulk metal Bi to two-dimensional well-crystallized BiOX (X = Cl, Br) micro- and nanostructures: Synthesis and characterization [J].
Deng, Zhengtao ;
Chen, Dong ;
Peng, Bo ;
Tang, Fangqiong .
CRYSTAL GROWTH & DESIGN, 2008, 8 (08) :2995-3003
[6]   Solar photocatalytic degradation of sulfanilamide by BiOCl/reduced graphene oxide nanocomposites: Mechanism and degradation pathways [J].
Dong, Shuying ;
Pi, Yunqing ;
Li, Qilu ;
Hu, Limin ;
Li, Yukun ;
Han, Xiao ;
Wang, Jingzhen ;
Sun, Jianhui .
JOURNAL OF ALLOYS AND COMPOUNDS, 2016, 663 :1-9
[7]   Recent developments in heterogeneous photocatalytic water treatment using visible light-responsive photocatalysts: a review [J].
Dong, Shuying ;
Feng, Jinglan ;
Fan, Maohong ;
Pi, Yunqing ;
Hu, Limin ;
Han, Xiao ;
Liu, Menglin ;
Sun, Jingyu ;
Sun, Jianhui .
RSC ADVANCES, 2015, 5 (19) :14610-14630
[8]   Hydrothermal synthesis of TiO2/Ti3C2 nanocomposites with enhanced photocatalytic activity [J].
Gao, Yupeng ;
Wang, Libo ;
Zhou, Aiguo ;
Li, Zhengyang ;
Chen, Jingkuo ;
Bala, Hari ;
Hu, Qianku ;
Cao, Xinxin .
MATERIALS LETTERS, 2015, 150 :62-64
[9]   Synthesis of few-layer MoS2 nanosheets-coated TiO2 nanosheets on graphite fibers for enhanced photocatalytic properties [J].
Hu, Xiaolin ;
Zhao, Hang ;
Tian, Jian ;
Gao, Jianxiong ;
Li, Yujie ;
Cui, Hongzhi .
SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2017, 172 :108-116
[10]   Black phosphorus quantum dots/attapulgite nanocomposite with enhanced photocatalytic performance [J].
Li, Xiazhang ;
Li, Feihong ;
Lu, Xiaowang ;
Zuo, Shixiang ;
Zhuang, Ziheng ;
Yao, Chao .
FUNCTIONAL MATERIALS LETTERS, 2017, 10 (06)