Graft modification of cellulose: Methods, properties and applications

被引:181
作者
Kang, Hongliang [1 ]
Liu, Ruigang [1 ]
Huang, Yong [1 ,2 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
[2] Chinese Acad Sci, Tech Inst Phys & Chem, Nat Res Ctr Engn Plast, Beijing 100190, Peoples R China
基金
中国国家自然科学基金;
关键词
Cellulose; Graft copolymers; Controlled/living radical polymerizations; Stimuli properties; Applications; TRANSFER RADICAL POLYMERIZATION; FRAGMENTATION CHAIN-TRANSFER; TRANSFER RAFT POLYMERIZATION; BIOLOGICALLY-ACTIVE POLYMERS; STRUCTURED POROUS FILMS; INITIATED ARGET-ATRP; G-PMMA COPOLYMERS; HEAVY-METAL IONS; SURFACE MODIFICATION; ETHYL CELLULOSE;
D O I
10.1016/j.polymer.2015.05.041
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
In this feature article, the recent progresses in the synthesis of cellulose graft copolymers with well-defined architecture were reviewed. The graft modification of cellulose using living/controlled polymerization methods was summarized. The properties of the cellulose graft copolymers can be adjusted by the cellulosic backbones and the chemical structure, graft density and length of the side chains. The stimuli-responsive properties of cellulose graft polymers are summarized and the stimuli-induced assemblies of cellulose graft copolymers can be used as carriers for drug and gene delivery. The graft modified cellulose materials can be applied in varies fields, including smart materials, adsorbents, and antibacterial materials and protein adsorption resistant materials. (C) 2015 Elsevier Ltd. All rights reserved.
引用
收藏
页码:A1 / A16
页数:16
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