Ring-Closing Metathesis in Aqueous Micellar Medium

被引：19

作者：

Laville, Lionel ^{[1
,2
]}

Charnay, Clarence ^{[1
]}

Lamaty, Frederic ^{[2
]}

Martinez, Jean ^{[2
]}

Colacino, Evelina ^{[2
]}

机构：

[1] Univ Montpellier 2, Inst Charles Gerhardt Montpellier ICGM, Equipe Agr Interfaces & Mat Energie, CNRS,UMR 5253, F-34095 Montpellier 5, France

[2] Univ Montpellier 2, Inst Biomol Max Mousseron IBMM, CNRS, UMR 5247,UM 1,UM 2, F-34095 Montpellier 5, France

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2012年 / 18卷 / 03期

关键词：

heterogeneous catalysis; micelles; reactions in water; ring-closing metathesis; ruthenium; surfactants; OLEFIN-METATHESIS; CATIONIC GEMINI; CATALYSTS; WATER; SURFACTANTS; POLYMERIZATION; SOLUBILIZATION; SOLVENTS; BEARING;

D O I：

10.1002/chem.201101985

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Underwater exploration: The ring-closing metathesis of N,N- diallyltosylamine (DATs) and diallyldiethyl malonate has been studied in aqueous micellar medium, at room temperature, in the presence of four different gemini cationic surfactants and various ruthenium catalysts (see figure). For the first time, the adsorption mechanisms and the reaction steps involved in this heterogeneous catalytic process were elucidated. Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：760 / 764

页数：5

共 43 条

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[Anonymous], ACS S SERIES

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