NMR and X-ray diffraction study of the crystalline structure of polyacrylonitrile

被引:0
作者
Berestova, SS
Shchirets, VS
Selikhova, VI
Polyakov, DK
Polyakova, GR
Zubov, YA
Polikarpov, VV
机构
来源
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B | 1996年 / 38卷 / 09期
关键词
D O I
暂无
中图分类号
O63 [高分子化学(高聚物)];
学科分类号
070305 ; 080501 ; 081704 ;
摘要
An attempt was made to establish the correlation between the tacticity of the molecular chain of polyacrylonitrile (PAN) obtained with different types of initiating systems and the crystallite dimensions. X-ray and NMR spectroscopic studies showed that the lateral dimensions of the crystallites are controlled mainly by the temperature of polymerization (and crystallization, respectively), whereas the longitudional dimensions along the molecular chain, by the polymer microtacticity.
引用
收藏
页码:1612 / 1613
页数:2
相关论文
共 50 条
[21]   EFFECT OF X-RAY COHERENCE ON CRYSTALLINE DIFFRACTION [J].
KUBENA, J .
CZECHOSLOVAK JOURNAL OF PHYSICS, 1968, 18 (06) :777-&
[22]   X-Ray Diffraction Study of High Hydrostatic Pressure on Crystalline Structure of Different Type Starches [J].
Liu Pei-ling ;
Shen Qun ;
Hu Xiao-song ;
Wu Ji-hong .
SPECTROSCOPY AND SPECTRAL ANALYSIS, 2012, 32 (09) :2579-2582
[23]   X-ray diffraction I: On the diffraction of xrays by crystalline solids [J].
Brittain, HG .
SPECTROSCOPY, 2000, 15 (06) :44-49
[24]   Structure study of BrHPLN by X-ray and neutron diffraction [J].
Kiyanagi, R ;
Kimura, H ;
Watanabe, M ;
Noda, Y ;
Mochida, T ;
Sugawara, T .
JOURNAL OF THE KOREAN PHYSICAL SOCIETY, 2005, 46 (01) :239-241
[25]   X-RAY DIFFRACTION STUDY OF LIQUID LEAD STRUCTURE [J].
ROMANOVA, AV ;
MELNIK, BA .
DOKLADY AKADEMII NAUK SSSR, 1969, 189 (02) :294-&
[26]   AN X-RAY DIFFRACTION STUDY OF STRUCTURE OF SILICA GLASS [J].
CARTZ, L .
ZEITSCHRIFT FUR KRISTALLOGRAPHIE, 1964, 120 (4-5) :241-&
[27]   X-RAY DIFFRACTION STUDY OF STRUCTURE IF NUCLEOHISTONE AND NUCLEOPROTAMINES [J].
WILKINS, MHF ;
ZUBAY, G .
JOURNAL OF MOLECULAR BIOLOGY, 1963, 7 (06) :756-&
[28]   Structure of octadecanol monolayers:: An x-ray diffraction study [J].
Brezesinski, G ;
Kaganer, VM ;
Möhwald, H ;
Howes, PB .
JOURNAL OF CHEMICAL PHYSICS, 1998, 109 (05) :2006-2010
[29]   X-RAY DIFFRACTION STUDY OF STRUCTURE OF ACTINOPHAGE DNA [J].
MOKULSKA.TD ;
STOLYARO.GS ;
MOKYLSKI.MA .
DOKLADY AKADEMII NAUK SSSR, 1965, 163 (03) :750-&
[30]   X-RAY DIFFRACTION STUDY OF THE STRUCTURE OF BACTERIAL FLAGELLA [J].
ASTBURY, WT ;
WEIBULL, C .
NATURE, 1949, 163 (4138) :280-282