Hydrogenation of carbon dioxide is promoted by a task-specific ionic liquid

被引:263
作者
Zhang, Zhaofu [1 ]
Xie, E. [1 ]
Li, Wenjing [1 ]
Hu, Suqin [1 ]
Song, Jinliang [1 ]
Jiang, Tao [1 ]
Han, Buxing [1 ]
机构
[1] Chinese Acad Sci, Inst Chem, Beijing Natl Lab Mol Sci, Beijing 100080, Peoples R China
关键词
carbon dioxide; heterogeneous catalysis; hydrogenation; ionic liquids; supported catalysts;
D O I
10.1002/anie.200704487
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
(Chemical Equation Presented) A basic hydrogenation catalyst: The combination of a basic ionic liquid (IL) and a supported ruthenium complex catalyzes the hydrogenation of CO2 with satisfactory activity and selectivity (see scheme). The resulting formic acid is easily collected and the ionic liquid and catalyst can be reused directly after an easy separation step. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码:1127 / 1129
页数:3
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