Palladium-Catalyzed Ligand-Free Suzuki-Miyaura Reaction of Aryl Fluorosulfates and Various Arylboron Compounds

被引：8
|
作者：
Li, Xinmin [1 ]
Zhang, Hang [1 ]
Feng, Fangfang [1 ]
Hu, Qinghong [1 ]
Yuan, Zeli [1 ]
机构：
[1] Zunyi Med Univ, Sch Pharm, Zunyi 563000, Peoples R China
来源：
CHEMISTRYSELECT | 2018年 / 3卷 / 43期
关键词：
Arylboron Compounds; Aryl Fluorosulfate; Ligand-free; One-pot; Suzuki-Miyaura reaction; COUPLING REACTION; CROSS-COUPLINGS; EFFICIENT; FLUORIDE; PHENOLS;
D O I：
10.1002/slct.201802120
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A practical and efficient protocol for the synthesis of biaryl products in good yields by a ligand-free palladium catalyzed Suzuki-Miyaura reaction of aryl fluorosulfates and various arylboron compounds has been developed. Moreover, we report a one-pot tandem method for conversion of phenol derivatives to aryl fluorosulfates, and subsequent cross-coupling to form biaryls.
引用
收藏
页码：12287 / 12290
页数：4
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