Synthesis and field emission of single-crystalline copper vanadate nanobelts

被引:14
作者
Mao, Changjie [1 ]
Wang, Xiaojie [1 ]
Wu, Xingcai [1 ]
Zhu, Jun-Jie [1 ]
Chen, Hong-Yuan [1 ]
机构
[1] Nanjing Univ, Sch Chem & Chem Engn, Key Lab Analyt Chem Life Sci, Nanjing 210093, Peoples R China
关键词
D O I
10.1088/0957-4484/19/03/035607
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Single-crystalline nanobelts of a nonstoichiometric compound Cu1.55V2O6.55, with a thickness of 40-60 nm, width of 50-300 nm and length of several micrometers, have been synthesized on a large scale by a hydrothermal method. The structures and morphologies of the nanobelts were characterized by x-ray powder diffraction, x-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and high-resolution transmission electron microscopy. A probable growth mechanism has also been discussed. The nanobelts exhibit a turn-on field of 11.0 V mu m(-1), which is defined as the macroscopic field required to produce a current density of 10 mu A cm(-2). It is anticipated that the nanobelts can serve as a candidate material for future field emitters.
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页数:6
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