The role of silver additives in gold-mediated C-H functionalisation

被引：41

作者：

Patrick, Scott R. ^{[1
]}

Boogaerts, Ine I. F. ^{[1
]}

Gaillard, Sylvain ^{[1
]}

Slawin, Alexandra M. Z. ^{[1
]}

Nolan, Steven P. ^{[1
]}

机构：

[1] Univ St Andrews, EaStCHEM Sch Chem, St Andrews KY16 9ST, Fife, Scotland

来源：

BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 7卷

基金：

英国工程与自然科学研究理事会;

关键词：

C-H functionalisation; gold catalyst; halide abstraction; N-heterocyclic carbene; silver salt; substrate activation; N-HETEROCYCLIC CARBENES; BOND FORMATION; CATALYSIS; ARYLATION; COMPLEXES; ACID;

D O I：

10.3762/bjoc.7.102

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The role of silver additives is examined in the context of gold-mediated functionalisation of aromatic C-H bonds. Doubt is cast on the commonly cited route of halide abstraction from gold and evidence of substrate activation is given.

引用

页码：892 / 896

页数：5

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