Anodic polarization behavior of copper in propylene carbonate

被引：29
作者：
Kawakita, J
Kobayashib, K
机构：
[1] Natl Res Inst Met, Tsukuba, Ibaraki 3050047, Japan
[2] Keio Univ, Fac Sci & Technol, Dept Chem, Kouhoku Ku, Yokohama, Kanagawa 2238522, Japan
来源：
JOURNAL OF POWER SOURCES | 2001年 / 101卷 / 01期
关键词：
copper; propylene carbonate; corrosion; FE-SEM; EQCM;
D O I：
10.1016/S0378-7753(01)00555-9
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Anodic polarization behavior of copper in propylene carbonate was investigated using electrochemical measurements, microscopic observations, elemental and gravimetric analyses. These results exhibited that anodic polarization of copper brought about oxidative dissolution of the metal substrate in competition with decomposition of the electrolyte on the metal surface. A reaction mechanism for oxidative dissolution was proposed with respect to both the charge transferring and the geometric form. (C) 2001 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：47 / 52
页数：6
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