A General Palladium-Catalyzed Aminocarbonylation of Phenols to Primary Benzamides via In Situ Generation of Aryl Nonaflates

被引:37
作者
Wu, Xiao-Feng [1 ,2 ]
Neumann, Helfried [1 ]
Beller, Matthias [1 ]
机构
[1] Univ Rostock, Leibniz Inst Katalyse eV, D-18059 Rostock, Germany
[2] Zhejiang Sci Tech Univ, Dept Chem, Hangzhou 310018, Zhejiang, Peoples R China
关键词
amides; aminocarbonylation reactions; aryl nonaflate; palladium; phenols; CONVERTING PRIMARY AMIDES; CARBONYLATION REACTIONS; HYDROXIDE CATALYST; COUPLING REACTIONS; AMMONIA SYNTHON; CARBON-MONOXIDE; ALLYL HALIDES; NITRILES; DEHYDRATION; CONVENIENT;
D O I
10.1002/chem.201102683
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Amides in mind! A novel palladium-catalyzed amino-carbonylation of in situ formed aryl nonaflates to give primary amides in moderate to excellent yields has been developed (see scheme). Copyright © 2012 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:419 / 422
页数:4
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