Autooxidation of hydrocarbons with oxygen in ionic liquids as solvents

被引:5
作者
Baj, Stefan [1 ]
Chrobok, Anna [1 ]
机构
[1] Silesian Tech Univ, Dept Chem Organ Technol & Petrochem, PL-44100 Gliwice, Poland
关键词
D O I
10.1002/kin.20315
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
The results of hydrocarbons autooxidation process carried out using several ionic liquids (IL) as solvents are demonstrated. Test studies to check the influence of ILs on this process showed that most ILs can accelerate the initiation rate of autooxidation. The results could be very useful for choosing an IL not only for autooxidation processes but also for catalytic oxidation systems. (C) 2008 Wiley Periodicals, Inc.
引用
收藏
页码:287 / 293
页数:7
相关论文
共 17 条
[1]   Ionic liquid crystals [J].
Binnemans, K .
CHEMICAL REVIEWS, 2005, 105 (11) :4148-4204
[2]   Hydrophobic, highly conductive ambient-temperature molten salts [J].
Bonhote, P ;
Dias, AP ;
Papageorgiou, N ;
Kalyanasundaram, K ;
Gratzel, M .
INORGANIC CHEMISTRY, 1996, 35 (05) :1168-1178
[3]  
Chrobok A, 2007, POL J CHEM, V81, P337
[4]   Oxidation of hydrocarbons by O2 in the presence of onium salts and onium ion-pair complexes as catalysts [J].
Csányi, LJ ;
Jáky, K ;
Kóta, Z ;
Páli, T .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2004, 209 (1-2) :59-68
[5]  
Denisov E.T., 2005, OXIDATION ANTIOXIDAN, DOI 10.1021/ja059854f
[6]   Ionic liquid (molten salt) phase organometallic catalysis [J].
Dupont, J ;
de Souza, RF ;
Suarez, PAZ .
CHEMICAL REVIEWS, 2002, 102 (10) :3667-3691
[7]   STRUCTURE OF 1-ETHYL-3-METHYLIMIDAZOLIUM HEXAFLUOROPHOSPHATE - MODEL FOR ROOM-TEMPERATURE MOLTEN-SALTS [J].
FULLER, J ;
CARLIN, RT ;
DELONG, HC ;
HAWORTH, D .
JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1994, (03) :299-300
[8]  
MILCHERT E, 1988, POL J APPL CHEM, V32, P171
[9]   Ionic liquids as solvents for catalyzed oxidations of organic compounds [J].
Muzart, J .
ADVANCED SYNTHESIS & CATALYSIS, 2006, 348 (03) :275-295
[10]   Ionic liquids: perspectives for organic and catalytic reactions [J].
Olivier-Bourbigou, H ;
Magna, L .
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2002, 182 (01) :419-437