Bronsted Acid-Catalyzed Dihydroxylation of Olefins in Aqueous Medium

被引：23
|
作者：
Rosatella, Andreia A. [1 ]
Afonso, Carlos A. M. [1 ]
机构：
[1] Univ Lisbon, Fac Farm, iMed UL, P-1649003 Lisbon, Portugal
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2011年 / 353卷 / 16期
关键词：
dihydroxylation; 1; 2-diols; hydrogen peroxide; olefins; water; SPHINGOMONAS SP HXN-200; NONHEME IRON CATALYSTS; HYDROGEN-PEROXIDE; ENANTIOSELECTIVE HYDROLYSIS; TRANS DIHYDROXYLATION; CIS-DIHYDROXYLATION; ORGANIC-SOLVENT; DIOLS; OXIDATION; ALKENES;
D O I：
10.1002/adsc.201100187
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The trans-dihydroxylation of olefins occurs efficiently by aqueous hydrogen peroxide catalyzed by p-toluenesulfonic acid at 50?degrees C, allowing the catalyst reuse and an outstanding substrate functional group tolerance such as tert-butoxycarbonylamino (BocNH), benzyloxycarbonylamino (CbzNH), benzyloxy (OBn), tosyloxy (OTs), hindered ketal, (2-trimethylsilyl)ethoxymethoxy (OSEM), benzylamino (NBz), benzyloxy (OBz) and free amino acid.
引用
收藏
页码：2920 / 2926
页数：7
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