Temperature stable dielectrics based on Cu doped Bi2Mg2/3Nb4/3O7 pyrochlore ceramics for LTCC

被引:42
作者
Guo, Qianyu [1 ]
Li, Lingxia [1 ]
Yu, Shihui [1 ]
Sun, Zheng [1 ]
Zheng, Haoran [1 ]
Li, Jiangteng [1 ]
Luo, Weijia [1 ]
机构
[1] Tianjin Univ, Minist Educ, Sch Microelect, Key Lab Adv Ceram & Machining Technol, Tianjin 300072, Peoples R China
基金
中国国家自然科学基金;
关键词
Dielectric properties; BMN ceramics; Low sintering; ELECTRICAL-PROPERTIES; CRYSTAL-CHEMISTRY; RELAXATION; PHASES; STRAIN;
D O I
10.1016/j.ceramint.2017.09.177
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Temperature stable dielectrics based on Cu doped Bi2Mg2/3Nb4/3O7 pyrochlore ceramics were prepared by conventional solid state reaction. Microstructure analysis indicates that all of the specimen maintain the cubic pyrochlore phase, a fluorite like phase of Bi3NbO7 and a Bi5Nb3O15 formed for Cu doping. The dielectric constant is dominated by densification of samples and secondary phases, while the dielectric loss is related by the secondary phases, grain boundaries, and leakage current characteristics. The (1-x)BMN - xCu0(x = 0.1 mol%) ceramic sintered at 925 degrees C shows excellent dielectric properties with dielectric constant of similar to 184.06, dielectric loss of similar to 0.0017 and near zero iota(epsilon) (-20 ppm/C) is obtained at sintering temperature of 925 degrees C, which could be a promising candidate for LTCC.
引用
收藏
页码:333 / 338
页数:6
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