Crystal structure of tris(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cobalt(III) tris(hexatluoro-phospnate) monohyarate

被引：0

作者：

Mani, Asma ^{[1
,2
]}

Belgaied, Jamel Eddine ^{[1
]}

Gasser, Gilles ^{[2
]}

Blacque, Olivier ^{[3
]}

机构：

[1] Carthage Univ, Natl Inst Appl Sci & Technol, EcoChim Lab, Tunis, Tunisia

[2] PSL Univ, Chim ParisTech, CNRS, Inst Chem Life & Hlth Sci,Lab Inorgan Chem Biol, F-75005 Paris, France

[3] Univ Zurich, Dept Chem, Winterthurerstr 190, CH-8057 Zurich, Switzerland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷

关键词：

crystal structure; cobalt(III) complexes; bathophenanthroline; photodynamic therapy; POLYPYRIDYL COMPLEXES; RUTHENIUM COMPLEXES; DNA-BINDING;

D O I：

10.1107/S2056989022001359

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Co(C72H48N6)](PF6)(3)center dot H2O, crystallizes with one tripositive complex molecule, three hexafluorophosphate anions and one solvent molecule of water in the asymmetric unit. The N-6 coordination set around the central Co-III atom defines a distorted octahedral environment. Four fluorine atoms of one hexafluorophosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697 (5) and 0.303 (5). In the crystal, intermolecular pi-pi stacking interactions, C-H center dot center dot center dot pi, C-H center dot center dot center dot F and O-H center dot center dot center dot F and interactions are present.

引用

页码：313 / +

页数：19

共 50 条

[41] Crystal structure of fac-trichlorido[tris(pyridin-2-yl-N)amine]chromium(III) [J].

Yamaguchi-Terasaki, Yukiko ;

Fujihara, Takashi ;

Nagasawa, Akira ;

Kaizaki, Sumio .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 :73-+

[42] Crystal structure and Hirshfeld surface analysis of (μ-2-{4-[(carboxylatomethyl)carbamoyl]benzamido}acetato-κ2O:O′)bis[bis(1,10-phenanthroline-κ2N,N′)copper(II)] dinitrate N,N′-(1,4-phenylenedicarbonyl)diglycine monosolvate octahydrate [J].

Pook, Niels-Patrick ;

Adam, Arnold ;

Gjikaj, Mimoza .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2019, 75 :667-+

[43] catena-Poly[[[(1,10-phenanthroline-κ2N,N′)zinc]-μ-pyridine-2,3-dicarboxylato-κ4N,O2:O2′,O3] monohydrate] [J].

Qin, Zhen-Hua ;

Lou, Shu-Fang ;

Wang, Na ;

Wang, Fu-Yu .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 :M864-U479

[44] Bis[4-oxido-2-oxo-2,3-dihydropyrimidin-1-ium-5-carboxylato(1.5-)-κ2O4,O5]bis(1,10-phenanthroline-κ2N,N′)dysprosium(III) dihydrate [J].

Liu, Xianlin ;

Xing, Huihui ;

Miao, Jing ;

Jia, Maomao ;

Chen, Zilu .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 :M1224-+

[45] Crystal structure of bisitris(1,10-phenanthroline-kappa N-2,N ')cobalt(II)] tetranitrate N,N '-(1,4-phenylenedicarbonyl)diglycine solvate octahydrate [J].

Pook, Niels-Patrick ;

Hentrich, Philipp ;

Gjikaj, Mimoza .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 :910-+

[46] Synthesis, spectral, electrochemical, crystal structure studies of two novel di-μ-halo-bis[halo(2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline)cadmium(II)] dimer complexes and their thermolysis to nanometal oxides [J].

Warad, Ismail ;

Abdoh, Muneer ;

Shivalingegowda, Naveen ;

Lokanath, Neartur Krishnappagowda ;

Salghi, Rachid ;

Al-Nuri, Mohammed ;

Jodeh, Shehdeh ;

Radi, Smaail ;

Hammouti, Belkheir .

JOURNAL OF MOLECULAR STRUCTURE, 2015, 1099 :323-329

[47] A novel dinuclear bismuth(III) coordination compound: bis(μ-pyridine-2,6-dicarboxylato)-κ4O2,N,O6:O6′;κ4O2:O2′,N,O6-bis[(azido-κN)(1,10-phenanthroline-κ2N,N′)bismuth(III)] tetrahydrate [J].

Zhang, Wei ;

Feng, Yu-Quan .

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY, 2014, 70 :562-+

[48] Crystal structure and Hirshfeld surface analysis of tris(acetohydrazide-κ2N,O)(nitrato-κO)(nitrato-κ2O,O′)terbium(III) nitrate [J].

Theppitak, Chatphorn ;

Laksee, Sakchai ;

Chainok, Kittipong .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2022, 78 :354-+

[49] Crystal structure of cis-aquachloridobis(1,10-phenanthroline-kappa N-2,N ') chromium(III) tetrachloridozincate monohydrate from synchrotron data [J].

Moon, Dohyun ;

Choi, Jong-Ha .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 :288-+

[50] Crystal structure of [tris(pyridin-2-ylmethyl)amine-kappa N-4]copper(II) bromide [J].

Bridgman, Emma C. ;

Doherty, Megan M. ;

Ellis, Kaleigh A. ;

Homer, Elizabeth A. ;

Lashbrook, Taylor N. ;

Mraz, Margaret E. ;

Pernesky, Gina C. ;

Vreeke, Emma M. ;

Oshin, Kayode D. ;

Oliver, Allen G. .

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2016, 72 :801-+

← 1 2 3 4 5 →