Crystal structure of tris(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cobalt(III) tris(hexatluoro-phospnate) monohyarate

被引：0
作者：
Mani, Asma [1 ,2 ]
Belgaied, Jamel Eddine [1 ]
Gasser, Gilles [2 ]
Blacque, Olivier [3 ]
机构：
[1] Carthage Univ, Natl Inst Appl Sci & Technol, EcoChim Lab, Tunis, Tunisia
[2] PSL Univ, Chim ParisTech, CNRS, Inst Chem Life & Hlth Sci,Lab Inorgan Chem Biol, F-75005 Paris, France
[3] Univ Zurich, Dept Chem, Winterthurerstr 190, CH-8057 Zurich, Switzerland
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷
关键词：
crystal structure; cobalt(III) complexes; bathophenanthroline; photodynamic therapy; POLYPYRIDYL COMPLEXES; RUTHENIUM COMPLEXES; DNA-BINDING;
D O I：
10.1107/S2056989022001359
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
The title compound, [Co(C72H48N6)](PF6)(3)center dot H2O, crystallizes with one tripositive complex molecule, three hexafluorophosphate anions and one solvent molecule of water in the asymmetric unit. The N-6 coordination set around the central Co-III atom defines a distorted octahedral environment. Four fluorine atoms of one hexafluorophosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697 (5) and 0.303 (5). In the crystal, intermolecular pi-pi stacking interactions, C-H center dot center dot center dot pi, C-H center dot center dot center dot F and O-H center dot center dot center dot F and interactions are present.
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页码：313 / +
页数：19
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