Crystal structure of tris(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cobalt(III) tris(hexatluoro-phospnate) monohyarate

被引：0

作者：

Mani, Asma ^{[1
,2
]}

Belgaied, Jamel Eddine ^{[1
]}

Gasser, Gilles ^{[2
]}

Blacque, Olivier ^{[3
]}

机构：

[1] Carthage Univ, Natl Inst Appl Sci & Technol, EcoChim Lab, Tunis, Tunisia

[2] PSL Univ, Chim ParisTech, CNRS, Inst Chem Life & Hlth Sci,Lab Inorgan Chem Biol, F-75005 Paris, France

[3] Univ Zurich, Dept Chem, Winterthurerstr 190, CH-8057 Zurich, Switzerland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷

关键词：

crystal structure; cobalt(III) complexes; bathophenanthroline; photodynamic therapy; POLYPYRIDYL COMPLEXES; RUTHENIUM COMPLEXES; DNA-BINDING;

D O I：

10.1107/S2056989022001359

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Co(C72H48N6)](PF6)(3)center dot H2O, crystallizes with one tripositive complex molecule, three hexafluorophosphate anions and one solvent molecule of water in the asymmetric unit. The N-6 coordination set around the central Co-III atom defines a distorted octahedral environment. Four fluorine atoms of one hexafluorophosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697 (5) and 0.303 (5). In the crystal, intermolecular pi-pi stacking interactions, C-H center dot center dot center dot pi, C-H center dot center dot center dot F and O-H center dot center dot center dot F and interactions are present.

引用

页码：313 / +

页数：19

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