Crystal structure of tris(4,7-diphenyl-1,10-phenanthroline-κ2N,N′)cobalt(III) tris(hexatluoro-phospnate) monohyarate

被引：0

作者：

Mani, Asma ^{[1
,2
]}

Belgaied, Jamel Eddine ^{[1
]}

Gasser, Gilles ^{[2
]}

Blacque, Olivier ^{[3
]}

机构：

[1] Carthage Univ, Natl Inst Appl Sci & Technol, EcoChim Lab, Tunis, Tunisia

[2] PSL Univ, Chim ParisTech, CNRS, Inst Chem Life & Hlth Sci,Lab Inorgan Chem Biol, F-75005 Paris, France

[3] Univ Zurich, Dept Chem, Winterthurerstr 190, CH-8057 Zurich, Switzerland

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2022年 / 78卷

关键词：

crystal structure; cobalt(III) complexes; bathophenanthroline; photodynamic therapy; POLYPYRIDYL COMPLEXES; RUTHENIUM COMPLEXES; DNA-BINDING;

D O I：

10.1107/S2056989022001359

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The title compound, [Co(C72H48N6)](PF6)(3)center dot H2O, crystallizes with one tripositive complex molecule, three hexafluorophosphate anions and one solvent molecule of water in the asymmetric unit. The N-6 coordination set around the central Co-III atom defines a distorted octahedral environment. Four fluorine atoms of one hexafluorophosphate anion are disordered over two sets of positions with site-occupancy factors of 0.697 (5) and 0.303 (5). In the crystal, intermolecular pi-pi stacking interactions, C-H center dot center dot center dot pi, C-H center dot center dot center dot F and O-H center dot center dot center dot F and interactions are present.

引用

页码：313 / +

页数：19

共 22 条

[1]

Alatrash N., 2020, CSD COMMUNICATION RE

[2] A new family of mono- and dicarboxylic ruthenium complexes [Ru(DIP)2(L2)]2+ (DIP=4,7-diphenyl-1,10-phenanthroline):: Synthesis, solution behavior, and X-ray molecular structure of trans-[Ru(DIP)2(MeOH)2][OTf]2 [J].

Caspar, Regis ;

Cordier, Christine ;

Waern, Jenny B. ;

Guyard-Duhayon, Carine ;

Gruselle, Michel ;

Le Floch, Pascal ;

Amouri, Hani .

INORGANIC CHEMISTRY, 2006, 45 (10) :4071-4078

[3] THE ANALYTICAL CALCULATION OF ABSORPTION IN MULTIFACETED CRYSTALS [J].

CLARK, RC ;

REID, JS .

ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 :887-897

[4] OLEX2: a complete structure solution, refinement and analysis program [J].

Dolomanov, Oleg V. ;

Bourhis, Luc J. ;

Gildea, Richard J. ;

Howard, Judith A. K. ;

Puschmann, Horst .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 2009, 42 :339-341

[5] CRYSTAL AND MOLECULAR-STRUCTURE OF A CHIRAL-SPECIFIC DNA-BINDING AGENT - TRIS(4,7-DIPHENYL-1,10-PHENANTHROLINE)RUTHENIUM(II) [J].

GOLDSTEIN, BM ;

BARTON, JK ;

BERMAN, HM .

INORGANIC CHEMISTRY, 1986, 25 (06) :842-847

[6] The Cambridge Structural Database [J].

Groom, Colin R. ;

Bruno, Ian J. ;

Lightfoot, Matthew P. ;

Ward, Suzanna C. .

ACTA CRYSTALLOGRAPHICA SECTION B-STRUCTURAL SCIENCE CRYSTAL ENGINEERING AND MATERIALS, 2016, 72 :171-179

[7] Mononuclear nickel(II) complexes coordinated by polypyridyl ligands [J].

Hadadzadeh, Hassan ;

Mansouri, Ghobad ;

Rezvani, Ali ;

Khavasi, Hamid R. ;

Skelton, Brian W. ;

Makha, Mohamed ;

Charati, Faramarz Rostami .

POLYHEDRON, 2011, 30 (15) :2535-2543

[8] Critical Overview of the Use of Ru(II) Polypyridyl Complexes as Photosensitizers in One-Photon and Two-Photon Photodynamic Therapy [J].

Heinemann, Franz ;

Karges, Johannes ;

Gasser, Gilles .

ACCOUNTS OF CHEMICAL RESEARCH, 2017, 50 (11) :2727-2736

[9] Strained Ruthenium Complexes Are Potent Light-Activated Anticancer Agents [J].

Howerton, Brock S. ;

Heidary, David K. ;

Glazer, Edith C. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (20) :8324-8327

[10] Metal-based photosensitizers for photodynamic therapy: the future of multimodal oncology? [J].

McFarland, Sherri A. ;

Mandel, Arkady ;

Dumoulin-White, Roger ;

Gasser, Gilles .

CURRENT OPINION IN CHEMICAL BIOLOGY, 2020, 56 :23-27

← 1 2 3 →