Pressure-induced collapse of ferromagnetism in cobalt up to 120 GPa as seen via x-ray magnetic circular dichroism

被引:29
作者
Torchio, R. [1 ,2 ]
Monza, A. [3 ]
Baudelet, F. [3 ]
Pascarelli, S. [1 ]
Mathon, O. [1 ]
Pugh, E. [4 ]
Antonangeli, D. [5 ]
Itie, J. Paul [3 ]
机构
[1] European Synchrotron Radiat Facil, F-38043 Grenoble, France
[2] Univ Roma Tre, Dipartimento Fis, Rome, Italy
[3] Synchrotron SOLEIL, F-91192 Gif Sur Yvette, France
[4] Univ Cambridge, Cavendish Lab, Cambridge CB3 0HE, England
[5] Univ Paris 06, Inst Mineral & Phys Milieux Condeses, CNRS, UMR 7590, F-75005 Paris, France
来源
PHYSICAL REVIEW B | 2011年 / 84卷 / 06期
关键词
BCC-HCP TRANSITION; ABSORPTION-SPECTROSCOPY; CRYSTAL-STRUCTURE; METALS; EDGE; CO; SUPERCONDUCTIVITY; FE;
D O I
10.1103/PhysRevB.84.060403
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The magnetism and structure of compressed Co has been studied up to 120 GPa using K-edge x-ray magnetic circular dichroism (XMCD) and x-ray absorption near edge spectroscopy (XANES). The XMCD signal decreases linearly with pressure and is totally suppressed around 120 GPa at ambient temperature. We detect local fcc-like atomic configurations starting from 80 GPa and at 120 GPa these represent at least 40% of the total. Supporting theoretical calculations indicate that the mixed hcp/fcc phase above 120 GPa is nonmagnetic. Comparison between the pressure evolution of magnetism and structure highlights major differences between the Fe and Co cases.
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页数:4
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