Diarylborenium cations: Synthesis, structure, and electrochemistry

被引：42

作者：

Chiu, Ching-Wen ^{[1
]}

Gabbai, Francois P. ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77843 USA

来源：

ORGANOMETALLICS | 2008年 / 27卷 / 07期

关键词：

D O I：

10.1021/om701249n

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Mes(2)BF and Ar(2)(N)BF (Ar(N) = 4-(Me(2)N)-2,6-Me(2)-C(6)H(2)) react with trimethylsilyltriflate and p-dimethylaminopyridine in chlorobenzene to afford the corresponding borenium salts [Mes(2)B-DMAP](+) OTf(-) ([1](+)OTf(-)) and [Ar(2)(N)B-DMAP](+) OTf(-)([2](+)OTf(-)), which have been fully characterized.

引用

页码：1657 / 1659

页数：3

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