Robust Bifunctional Core-Shell MOF@POP Catalyst for One-Pot Tandem Reaction

被引：29

作者：

Qi, Mei-Hong ^{[1
]}

Gao, Ming-Liang ^{[1
]}

Liu, Lin ^{[1
]}

Han, Zheng-Bo ^{[1
]}

机构：

[1] Liaoning Univ, Coll Chem, Shenyang 110036, Liaoning, Peoples R China

来源：

INORGANIC CHEMISTRY | 2018年 / 57卷 / 23期

基金：

中国国家自然科学基金;

关键词：

METAL-ORGANIC FRAMEWORK; EFFICIENT; MICROSPHERES; SEPARATION;

D O I：

10.1021/acs.inorgchem.8b02303

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new bifunctional acid-base catalyst, core-shell UiO-66@SNW-1, with robust chemical and thermal stability, recyclability, and durable catalytic activity is synthesized by a convenient, universal strategy. Interestingly, this hybrid material can effectively catalyze deacetalization-Knoevenagel condensation reaction in the presence of excellent compartmentalization to spatially isolate opposing acid-base sites.

引用

页码：14467 / 14470

页数：4

共 34 条

[1]

Beyzavi MH, 2015, J AM CHEM SOC, V137, P13624, DOI [10.1021/jacs.5b03440, 10.1021/jacs.5b08440]

[2] A trifunctional mesoporous silica-based, highly active catalyst for one-pot, three-step cascade reactions [J].

Biradar, Ankush V. ;

Patil, Vijayshinha S. ;

Chandra, Prakash ;

Doke, Dhananjay S. ;

Asefa, Tewodros .

CHEMICAL COMMUNICATIONS, 2015, 51 (40) :8496-8499

[3] Metal Organic Frameworks as Versatile Hosts of Au Nanoparticles in Heterogeneous Catalysis [J].

Dhakshinamoorthy, Amarajothi ;

Asiri, Abdullah M. ;

Garcia, Hermenegildo .

ACS CATALYSIS, 2017, 7 (04) :2896-2919

[4] Mixed-metal or mixed-linker metal organic frameworks as heterogeneous catalysts [J].

Dhakshinamoorthy, Amarajothi ;

Asiri, Abdullah M. ;

Garcia, Hermenegildo .

CATALYSIS SCIENCE & TECHNOLOGY, 2016, 6 (14) :5238-5261

[5] Cascade Reactions Catalyzed by Metal Organic Frameworks [J].

Dhakshinamoorthy, Amarajothi ;

Garcia, Hermenegildo .

CHEMSUSCHEM, 2014, 7 (09) :2392-2410

[6] Anionic metal-organic framework for high-efficiency pollutant removal and selective sensing of Fe(III) ions [J].

Gao, Ming-Liang ;

Wei, Na ;

Han, Zheng-Bo .

RSC ADVANCES, 2016, 6 (65) :60940-60944

[7] Multifunctional metal-organic frameworks constructed from meta-benzenedicarboxylate units [J].

He, Yabing ;

Li, Bin ;

O'Keeffe, Michael ;

Chen, Banglin .

CHEMICAL SOCIETY REVIEWS, 2014, 43 (16) :5618-5656

[8] Chemical, thermal and mechanical stabilities of metal-organic frameworks [J].

Howarth, Ashlee J. ;

Liu, Yangyang ;

Li, Peng ;

Li, Zhanyong ;

Wang, Timothy C. ;

Hupp, JosephT. ;

Farha, Omar K. .

NATURE REVIEWS MATERIALS, 2016, 1 (03)

[9] Systematic Engineering of Single Substitution in Zirconium Metal-Organic Frameworks toward High-Performance Catalysis [J].

Huang, Ning ;

Yuan, Shuai ;

Drake, Hannah ;

Yang, Xinyu ;

Pang, Jiandong ;

Qin, Junsheng ;

Li, Jialuo ;

Zhang, Yingmu ;

Wang, Qi ;

Jiang, Donglin ;

Zhou, Hong-Cai .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (51) :18590-18597

[10] Fe3O4@MOF core-shell magnetic microspheres as excellent catalysts for the Claisen-Schmidt condensation reaction [J].

Ke, Fei ;

Qiu, Ling-Guang ;

Zhu, Junfa .

NANOSCALE, 2014, 6 (03) :1596-1601

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