An unusual N-alkylation reaction during the oxidative addition of hexafluoroacetone and tetrachloro-o-benzoquinone to P-bis(2-chloroethyl)amino-substituted lambda(3) P-compounds

被引：0

作者：

Neda, I ^{[1
]}

Melnicky, C ^{[1
]}

Vollbrecht, A ^{[1
]}

Schmutzler, R ^{[1
]}

机构：

[1] TECH UNIV BERLIN,INST ANORGAN & ANALYT CHEM,D-38023 BRAUNSCHWEIG,GERMANY

来源：

SYNTHESIS-STUTTGART | 1996年 / 04期

关键词：

oxidative addition; N-alkylation; benzodiaza-lambda(3)-phosphorinones; tricyclic phosphoranes;

D O I：

暂无

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The reaction of 2,3-dihydro-1,3,2-benzodiazaphosphinin-4(1H)-ones 1a-d with hexafluoroacetone took an unusual course with formation of the tricyclic phosphoranes 5a-d. Similar products 6a, c, d were obtained by treatment of 1a, c, d with tetrachloro-o-benzoquinone.

引用

页码：473 / &

页数：3

共 12 条

[1] ORTHO-BENZOQUINONE ADDUCTS, REARRANGEMENT AND ELIMINATION-REACTIONS OF 1,1,3-TRIMETHYL-1,3,2-DIAZAPHOSPHOLIDIN-1-IUM SALTS
BECKER, W
SCHIEBEL, HM
SCHMUTZLER, R
[J]. CHEMISCHE BERICHTE-RECUEIL, 1992, 125 (04): : 793 - 800
[2] HEXAFLUOROACETONE ADDUCTS OF 1-PHENYLPHOSPHETANS - BARRIER TO PLACING A 4-MEMBERED RING DIEQUATORIAL IN A TRIGONAL BIPYRAMID NUCLEAR MAGNETIC RESONANCE STUDY
DUFF, RE
ORAM, RK
TRIPPETT, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (17): : 1011 - &
[3] Evangelidou-Tsolis E., 1974, PHOSPHORUS, V4, P121
[4] MARK V, 1967, TOPICS PHOSPHORUS CH, V5, P227
[5] COMPOUNDS WITH 1,3,2-BENZODIAZAPHOSPHORINAN-4-ONE STRUCTURE - SYNTHESIS OF NEW N,N-DIMETHYLAMIMNO-SUBSTITUTED AND BIS-2-CHLOETHYLAMINO-SUBSTITUTED DERIVATIVES WITH TRICOORDINATED, TETRACOORDINATED AND PENTACOORDINATED PHOSPHORUS
NEDA, I
FISCHER, A
JONES, PG
SCHMUTZLER, R
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 78 (1-4): : 271 - 287
[6] PREPARATION AND CHARACTERIZATION OF 2-CHLOROETHYL-SUBSTITUTED BENZODIAZAPHOSPHORINANONES
NEDA, I
KAUKORAT, T
SCHMUTZLER, R
[J]. PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1993, 84 (1-4): : 205 - 216
[7] NEDA I, 1996, Z ANORG ALLG CHEM, V622, P600
[8] REACTIONS OF 1-SUBSTITUTED 2,2,3,4,4-PENTAMETHYLPHOSPHETANS WITH HEXAFLUOROACETONE AND F-19 NUCLEAR MAGNETIC-RESONANCE SPECTRA OF RESULTING 1,3,2-DIOXAPHOSPHOLANS
ORAM, RK
TRIPPETT, S
[J]. JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1973, (12): : 1300 - 1310
[9] RAMIREZ F, 1974, SYNTHESIS-STUTTGART, P90
[10] REACTION OF TERTIARY PHOSPHINES WITH HEXAFLUOROACETONE AND WITH O-QUINONES . ATTACK BY PHOSPHORUS ON CARBONYL OXYGEN AND ISOLATION OF 2,2,2-TRIALKYL-2,2-DIHYDRO-1,3,2-DIOXAPHOSPHOLANES
RAMIREZ, F
SMITH, CP
PILOT, JF
GULATI, AS
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1968, 33 (10) : 3787 - &

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