Synergistic Photoredox/Transition-Metal Catalysis for Carbon-Carbon Bond Formation Reactions

被引:69
作者
De Abreu, Maxime [1 ]
Belmont, Philippe [1 ]
Brachet, Etienne [1 ]
机构
[1] Univ Paris, Fac Pharm Paris, Team PNAS, CNRS,UMR 8038,CiTCoM, 4 Ave Observ, F-75006 Paris, France
关键词
Photocatalysis; Metals; Radicals; Carbon-carbon; Dual metallaphotoredox; VISIBLE-LIGHT PHOTOREDOX; SINGLE-ELECTRON TRANSMETALATION; C-H ARYLATION; ALPHA-AMINO-ACIDS; MERGING PHOTOREDOX; DUAL CATALYSIS; CARBOXYLIC-ACIDS; ARYL HALIDES; NICKEL CATALYSIS; METALLAPHOTOREDOX CATALYSIS;
D O I
10.1002/ejoc.201901146
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Carbon-carbon bond formation reactions are of longstanding interest in organic chemistry. Improvements of the methods targeting its creation are still being performed, especially thanks to the development of innovative methodologies in transition metal catalysis and photocatalysis. This review will tackle the combination of transition metal and photoredox cycles to create carbon-carbon bonds, focusing on the four transition metals most reported in the literature in this domain: Ni, Pd, Au and Cu.
引用
收藏
页码:1327 / 1378
页数:52
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