Synthesis and Solid State Structures of Two New Copper(II) Complexes of Schiff Bases Derived from Furfuryl and Tetrahydrofurfurylamine

被引：9

作者：

Chen, W. ^{[1
,2
]}

Miao, P. ^{[1
]}

Li, Y. G. ^{[1
]}

Zhu, H. L. ^{[1
,2
]}

Zeng, Q. F. ^{[1
]}

机构：

[1] Wuhan Text Univ, Minist Educ, Engn Res Ctr Clean Prod Text Printing, Wuhan 430073, Peoples R China

[2] Nanjing Univ, Inst Funct Biomol, State Key Lab Pharmaceut Biotechnol, Nanjing 210093, Peoples R China

来源：

RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 36卷 / 12期

基金：

中国国家自然科学基金;

关键词：

TRANSITION-METAL-COMPLEXES; CRYSTAL-STRUCTURES; ELECTROCHEMICAL PROPERTIES; XANTHINE-OXIDASE; LIGANDS; COORDINATION; CLEAVAGE; NI; CU; PLANAR;

D O I：

10.1134/S1070328410120110

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two Schiff base copper(II) complexes, bis(N-furfurylsalicylaldiminato)copper(II) (I) and bis(N-tetrahydrofurfurylsalicylaldiminato)copper(II) (II), were synthesized and their solid state structures were determined by X-ray crystallography. Complex I has a square planar geometry. In contrast, complex II displays a distorted square planar geometry. Thus, the geometry around copper in the solid state structures of I and II is determined by a combination of steric and electronic effects, as well as by crystal packing forces.

引用

页码：929 / 933

页数：5

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