catena-Poly[[(1,10-phenanthroline)lead(II)]bis(μ-5-chloro-2-hydroxybenzoato)]

被引：3

作者：

Yang, Lei ^{[1
]}

Li, Bing ^{[2
]}

Xue, Qing ^{[1
]}

Huo, Yu ^{[1
]}

Wang, Gaopeng ^{[1
]}

机构：

[1] Henan Polytech Univ, Dept Phys Chem, Jiaozuo 454150, Peoples R China

[2] Zhejiang Forestry Univ, Dept Chem, Linan 311300, Peoples R China

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2010年 / 66卷

关键词：

D O I：

10.1107/S1600536810023561

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title polymer, [Pb(C(7)H(4)ClO(3))(2)(C(12)H(8)N(2))] (n) , the Pb(II) ion displays a distorted pseudo-octahedral coordination geometry. The metal center is coordinated by six O atoms from four 5-chlorosalicylate ligands and two N atoms from a chelating phenanthroline ligand. The polymeric structure is built up from bridging carboxylate O atoms, forming chains along [100]. The crystal structure is stabilized by pi-pi interactions between the 1,10-phenanthroline and 5-chlorosalicylate ligands, the shortest centroid-centroid separation between neighbouring aromatic rings being 3.652 (1) A.

引用

页码：M987 / U1164

页数：12

共 4 条

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Wen, Decai ;

Xie, Jing ;

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ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 :M851-U43

[4] Aquabis(5-chlorosalicylato-κO)(1,10-phenanthroline-κ2N,N′)zinc(II) [J].

Wen, Decai ;

Ying, Shaoming .

ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 :M2407-U1456

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