Poly(1,20-eicosanediyl 2,5-furandicarboxylate), a biodegradable polyester from renewable resources

被引：47

作者：

Soares, Maria J. ^{[1
,2
]}

Dannecker, Patrick-Kurt ^{[3
]}

Vilela, Carla ^{[1
,2
]}

Bastos, Jose ^{[1
,2
]}

Meier, Michael A. R. ^{[3
]}

Sousa, Andreia F. ^{[1
,2
,4
]}

机构：

[1] Univ Aveiro, CICECO Aveiro Inst Mat, P-3810193 Aveiro, Portugal

[2] Univ Aveiro, Dept Chem, P-3810193 Aveiro, Portugal

[3] KIT, IOC, Mat Wissensch Zentrum MZE, Str Forum 7, D-76131 Karlsruhe, Germany

[4] Univ Coimbra, Dept Chem Engn, CEMUC, P-3030790 Coimbra, Portugal

来源：

EUROPEAN POLYMER JOURNAL | 2017年 / 90卷

关键词：

2,5-Furandicarboxylic acid; 1,20-Eicosanediol; Very-long-chain diols; Biodegradable; Renewable resources; ALIPHATIC POLYESTERS; POLY(ETHYLENE OXIDE); BIOBASED POLYESTERS; THERMAL-DEGRADATION; TERNARY BLENDS; ACID; SUBERIN; POLYMERS; MONOMERS; FURAN;

D O I：

10.1016/j.eurpolymj.2017.03.023

中图分类号：

O63 [高分子化学（高聚物）];

学科分类号：

070305 ; 080501 ; 081704 ;

摘要：

Furanic-very-long-aliphatic polyester based on 2,5-furandicarboxylic acid and 1,20-eicosanediol was introduced as a new polymer from renewable resources that is biodegradable. This poly (1,20-eicosanediyl 2,5-furandicarboxylate) (PE20F) was extensively characterised by means of FTIR, H-1 and C-13 NMR, SEC, DSC, TGA, sorption experiments, water contact angles and biodegradation tests. PE20F has a melting temperature of 107 degrees C, a glass transition around 7 degrees C and moreover has a water contact angle of 96 degrees, but nevertheless PE20F biodegraded.

引用

页码：301 / 311

页数：11

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