Recent Progress on Chemical Species of Uranium in Molten Chlorides

被引:3
作者
Liu, Yichuan [1 ,2 ]
Liu, Yalan [2 ]
Jiang, Shilin [2 ]
Li, Mei [1 ]
Shi, Weiqun [2 ]
机构
[1] Harbin Engn Univ, Coll Mat Sci & Chem Engn, Harbin 150001, Peoples R China
[2] Chinese Acad Sci, Inst High Energy Phys, Beijing 100049, Peoples R China
基金
中国国家自然科学基金;
关键词
pyrochemical reprocessing; molten salt; chemical species; uranium; ELECTRONIC-ABSORPTION-SPECTRA; KCL EUTECTIC MELT; REDOX EQUILIBRIUM; 1ST PRINCIPLES; X-RAY; IONS; LANTHANIDES; DIOXIDE; UCL3; NEODYMIUM(III);
D O I
10.6023/A21070341
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
High-temperature molten salt electrolysis based pyrochemical reprocessing of spent nuclear fuel has certain advantages for advanced nuclear fuel cycle, which is usually carried out in a high-temperature chloride molten salt system, and actinides (Ans) are recovered and separated over lanthanides (Lns) via electrolysis in molten salt. Among them, the separation and recovery of uranium from fission products (FPs) is one of the key tasks. To optimize the separation process, it is necessary to deeply understand the relationship between electrochemical properties and chemical species of uranium in molten salt. Hence, it is very important to carry out the study of the chemical species of uranium in molten chlorides. In this review, the research progresses on chemical species of uranium in molten chlorides have been summarized and sorted. In addition, future perspectives upon actinide chemical species in molten salt have been given.
引用
收藏
页码:1425 / 1437
页数:13
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