New cadmium(II) and iron(II) coordination frameworks incorporating a di(4-pyridyl)isoindoline ligand

被引：8

作者：

Mulyana, Y

Kepert, CJ ^{[1
]}

Lindoy, LF

McMurtrie, JC

机构：

[1] Univ Sydney, Ctr Heavy Metals Res, Sch Chem, Sydney, NSW 2006, Australia

[2] Queensland Univ Technol, Sch Phys & Chem Sci, Brisbane, Qld 4001, Australia

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2005年 / 12期

关键词：

cadmium; iron molecular; framework;

D O I：

10.1002/ejic.200500108

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The metal-directed assembly of molecular frameworks incorporating the ditopic heterocyclic ligand 1-(4-pyridyl)imino-2(4-pyridyl)isoindohne (L) associated with nonlinear coordination vectors, is presented. Two infinite metallo-arrays of empirical formula [CdL(NO3)(2)(EtOH)](n)center dot(1.4H(2)O)(n) and [FeL2(NCS)(2)](n)center dot{(2CHClCCl(2))center dot(1.4MeOH)center dot(2.9H(2)O)}(n) have been characterised. The X-ray structures of both arrays are reported. The cadmium(II) framework consists of co-aligned 1D coordinate polymer chains while the iron(II) framework consists of rhombic grids with 2D polymeric connectivity. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)

引用

页码：2470 / 2475

页数：6

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