Hemp-based all-cellulose composites through ionic liquid promoted controllable dissolution and structural control

被引:24
作者
Chen, Ke [1 ]
Xu, Weixin [2 ]
Ding, Yun [2 ]
Xue, Ping [1 ]
Sheng, Pinghou [3 ]
Qiao, Hui [2 ]
He, Jimin [1 ]
机构
[1] Beijing Univ Chem Technol, Coll Mech & Elect Engn, Beijing 100029, Peoples R China
[2] Beijing Univ Chem Technol, Coll Mat Sci & Engn, Beijing 100029, Peoples R China
[3] China Text Acad, State Key Lab Biobased Fiber Mfg Technol, Beijing 100025, Peoples R China
关键词
All-cellulose composites; Ionic liquids; Mechanical properties; Structure-Property relations; FIBER;
D O I
10.1016/j.carbpol.2020.116027
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
All-cellulose composites (ACC) were effectively prepared by a low energy consumption strategy. The ionic liquid of 1-butyl-3-methylimidazolium chloride (BMIMC1) was used to immerse hemp fabric before hot-pressing process at a relative low temperature. The tensile strength and modulus of prepared ACC reached 81.1 MPa and 1.50 GPa, respectively. The dissolution mechanism of ACC by BMIMCl was successfully observed by the cooperation of optical microscope and polarizing microscope. Scanning electron microscope (SEM), X-ray diffraction (XRD), thermal gravimetric analysis (TGA) and mechanical testing were carried out to investigate the effect of hotpressing temperature on the properties of ACC samples. ACC sample exhibited the highest mechanical performance at hot-pressing temperature of 120 degrees C. This work provided a simple and promising pathway for industrial application of high performance and environmental-friendly all-cellulose composites.
引用
收藏
页数:7
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