B(C6F5)3-Promoted hydrogenations of N-heterocycles with ammonia borane

被引：61
|
作者：
Ding, Fangwei [1 ,2 ]
Zhang, Yiliang [1 ,2 ]
Zhao, Rong [1 ,2 ]
Jiang, Yanqiu [1 ]
Bao, Robert Li-Yuan [1 ,2 ]
Lin, Kaifeng [1 ]
Shi, Lei [1 ,2 ]
机构：
[1] Harbin Inst Technol, Sch Chem & Chem Engn, MIIT Key Lab Crit Mat Technol New Energy Convers, Harbin 150001, Heilongjiang, Peoples R China
[2] Harbin Inst Technol, Shenzhen Grad Sch, Shenzhen 518055, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 66期
基金：
中国国家自然科学基金;
关键词：
FRUSTRATED LEWIS PAIRS; CATALYTIC-HYDROGENATION; REDUCTION; QUINOLINES; PYRIDINES; BOND; REACTIVITY; DIHYDROGEN; ALDEHYDES; DESIGN;
D O I：
10.1039/c7cc04709f
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A transition-metal-free method for the B(C6F5)(3)-promoted hydro-genations of N-heterocycles using ammonia borane under mild reaction conditions has been developed. The reaction affords a broad range of hydrogenated products in moderate to good yields. The enantioselective versions for the corresponding products were also investigated via our approach, showing good feasibility.
引用
收藏
页码：9262 / 9264
页数：3
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