Ultrasonic speeds and isentropic compressibilities of {difurylmethane + (C1-C6) n-alkanol} binary mixtures at T=298.15 K

被引:6
|
作者
Mmereki, B. T. [1 ]
Oathotse, I. [1 ]
Ddamba, W. A. A. [1 ]
机构
[1] Univ Botswana, Dept Chem, Gaborone, Botswana
来源
JOURNAL OF CHEMICAL THERMODYNAMICS | 2010年 / 42卷 / 11期
关键词
Difurylmethane; Alkan-1-ols; Excess isentropic compressibility; Excess intermolecular free length; Dipole-dipole interactions; VOLUMETRIC PROPERTIES; BINARY-MIXTURES; MOLAR VOLUMES; PLUS; METHANOL; DIFURYLMETHANE; 25-DEGREES-C; VISCOSITIES; DENSITIES; SYSTEMS;
D O I
10.1016/j.jct.2010.05.016
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities (rho), and ultrasonic speeds (u) of iclifurylmethane + (methanol or ethanol or propan-1-ol or butan-1-ol or pentan-1-ol or hexan-1-01)) binary mixtures have been measured over the entire composition range at T= 298.151< and atmospheric pressure. Excess isentropic compressibility coefficient, 4, excess ultrasonic speeds, uE and excess intermolecular free length, 4, of each binary system were calculated and correlated by the Redlich-Kister equation. The results are discussed in terms of possible intermolecular interactions and structural effects. o 2010 Published by Elsevier Ltd.
引用
收藏
页码:1346 / 1351
页数:6
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