Engineering of magnetically separable ZnFe2O4@ TiO2 nanofibers for dye-sensitized solar cells and removal of pollutant from water

被引:46
作者
Al-Meer, Saeed [1 ]
Ghouri, Zafar Khan [1 ]
Elsaid, Khaled [2 ]
Easa, Ahmed [1 ]
Al-Qahtani, Muneera Th. [1 ]
Akhtar, M. Shaheer [3 ]
机构
[1] Qatar Univ, Cent Labs, POB 2713, Doha, Qatar
[2] Texas A&M Univ Qatar, Chem Engn Program, POB 23874, Doha, Qatar
[3] Chonbuk Natl Univ, New & Renewable Energy Mat Dev Ctr NewREC, Jeonju 54896, South Korea
关键词
Zinc ferrite; Electrospinning; Hydrothermal method; Photoanode; Solar cells; Photocatalyst; DOPED TIO2; EFFICIENCY ENHANCEMENT; NANOCOMPOSITE; NANOPARTICLES; REDUCTION; ELECTRODE; ZNFE2O4/TIO2; DEGRADATION; PHOTOANODE; DIOXIDE;
D O I
10.1016/j.jallcom.2017.06.211
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
In this study, magnetic Zinc Ferrite (ZnFe2O4)@ TiO2 nanofibers were prepared by low cost and nontoxic route; hydrothermal technique followed by electrospinning process. The prepared magnetic ZnFe2O4@ TiO2 nanofibers were morphologically and structurally analyzed by X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FTIR), field emission scanning electron microscope (FESEM), transmission electron microscope (TEM), and thermal gravimetric analysis (TGA). The prepared magnetic ZnFe2O4@ TiO2 nanofibers were utilized as photoanode for the fabrication of dye-sensitized solar cells (DSSCs) and presented applicable performance with 4.2% overall conversion efficiency with high short circuit current density (JSC) of 10.16 mA/cm(2). The maximum similar to 42% incident photo-to-current conversion efficiency (IPCE) value was also recorded at 530 nm. In addition, ZnFe2O4@ TiO2 nanofibers were not only possessed the good conversion efficiency, but also shown excellent photocatalytic efficiency with magnetic properties towards the dye remediation. Prepared ZnFe2O4@ TiO2 nanofibers can be considered as a promising material for energy conversion and environmental applications. (C) 2017 Elsevier B.V. All rights reserved.
引用
收藏
页码:477 / 483
页数:7
相关论文
共 42 条
  • [1] Highly efficient dye-sensitized solar cells with a titania thin-film electrode composed of a network structure of single-crystal-like TiO2 nanowires made by the "oriented attachment" mechanism
    Adachi, M
    Murata, Y
    Takao, J
    Jiu, JT
    Sakamoto, M
    Wang, FM
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (45) : 14943 - 14949
  • [2] ZnO hollow nano-baskets for mineralization of cationic dye
    Ameen, Sadia
    Akhtar, M. Shaheer
    Shin, Hyung Shik
    [J]. MATERIALS LETTERS, 2016, 183 : 329 - 333
  • [3] Solution-processed CeO2/TiO2 nanocomposite as potent visible light photocatalyst for the degradation of bromophenol dye
    Ameen, Sadia
    Akhtar, M. Shaheer
    Seo, Hyung-Kee
    Shin, Hyung-Shik
    [J]. CHEMICAL ENGINEERING JOURNAL, 2014, 247 : 193 - 198
  • [4] Advanced ZnO-graphene oxide nanohybrid and its photocatalytic Applications
    Ameen, Sadia
    Akhtar, M. Shaheer
    Seo, Hyung-Kee
    Shin, Hyung Shik
    [J]. MATERIALS LETTERS, 2013, 100 : 261 - 265
  • [5] NixCo1-x alloy nanoparticle-doped carbon nanofibers as effective non-precious catalyst for ethanol oxidation
    Barakat, Nasser A. M.
    Motlak, Moaaed
    Elzatahry, Ahmed A.
    Khalil, Khalil Abdelrazek
    Abdelghani, Emad A. M.
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2014, 39 (01) : 305 - 316
  • [6] Efficiency enhancement of flexible dye-sensitized solar cell with sol-gel formed Nb2O5 blocking layer
    Cho, Tae-Yeon
    Ko, Kwan-Woo
    Yoon, Soon-Gil
    Sekhon, Satpal Singh
    Kang, Man Gu
    Hong, Young-Sik
    Han, Chi-Hwan
    [J]. CURRENT APPLIED PHYSICS, 2013, 13 (07) : 1391 - 1396
  • [7] Preparation of ZnO-coated TiO2 electrodes using dip coating and their applications in dye-sensitized solar cells
    Chou, Chuen-Shii
    Chou, Feng-Cheng
    Kang, Jhe-Yuan
    [J]. POWDER TECHNOLOGY, 2012, 215-16 : 38 - 45
  • [8] Efficiency enhancement in DSSC using metal nanoparticles: A size dependent study
    Deepa, K. G.
    Lekha, P.
    Sindhu, S.
    [J]. SOLAR ENERGY, 2012, 86 (01) : 326 - 330
  • [9] Enhancement of the absorbance figure of merit in amorphous-silicon p-i-n solar cell by using optimized intermediate metallic layers
    Ferhati, H.
    Djeffal, F.
    Srairi, F.
    [J]. OPTIK, 2017, 130 : 473 - 480
  • [10] Total oxidation of toluene on ferrite-type catalysts
    Florea, M.
    Alifanti, M.
    Parvulescu, V. I.
    Mihaila-Tarabasanu, D.
    Diamandescu, L.
    Feder, M.
    Negrila, C.
    Frunza, L.
    [J]. CATALYSIS TODAY, 2009, 141 (3-4) : 361 - 366