Rice husk-derived carbon-silica supported Ni catalysts for selective hydrogenation of biomass-derived furfural and levulinic acid

被引:51
|
作者
Madduluri, Venkata Rao [1 ]
Mandari, Kotesh Kumar [2 ]
Velpula, Venkateshwarlu [1 ]
Varkolu, Mohan [1 ]
Kamaraju, Seetha Rama Rao [1 ]
Kang, Misook [2 ]
机构
[1] CSIR Indian Inst Chem Technol, Catalysis Lab, Hyderabad 500607, Telangana, India
[2] Yeungnam Univ, Coll Nat Sci, Dept Chem, 280 Daehak Ro, Gyongsan 38541, Gyeongbuk, South Korea
基金
新加坡国家研究基金会;
关键词
Hydrogenation; Furfural; Levulinic acid; Rice husk derived carbon-silica; Ni catalysts; GAMMA-VALEROLACTONE; MESOPOROUS SILICA; COPPER-CATALYSTS; ASH; ADSORPTION; ALCOHOL; HYDROCYCLIZATION; NANOPARTICLES; CONVERSION; STABILITY;
D O I
10.1016/j.fuel.2019.116339
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
To achieve good activity in a continuous vapor phase hydrogenation of biomass-derived molecules via levulunic acid and furfural over rice husk derived C-SiO2 supported nickel (5-30 wt% Ni loading catalysts), synthesized by wet impregnation method have been used for the first time. Among the catalysts, 15 wt% Ni/C-SiO2 catalyst exhibited good activity in both furfural and levulunic acid hydrogenations due to higher Ni dispersion and smaller particle size. The activity exhibited by 15 wt% Ni/C-SiO2 for both hydrogenation reactions is either superior or on par with the catalysts cited in the literature under similar reaction conditions.
引用
收藏
页数:10
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