Rice husk-derived carbon-silica supported Ni catalysts for selective hydrogenation of biomass-derived furfural and levulinic acid

被引:54
作者
Madduluri, Venkata Rao [1 ]
Mandari, Kotesh Kumar [2 ]
Velpula, Venkateshwarlu [1 ]
Varkolu, Mohan [1 ]
Kamaraju, Seetha Rama Rao [1 ]
Kang, Misook [2 ]
机构
[1] CSIR Indian Inst Chem Technol, Catalysis Lab, Hyderabad 500607, Telangana, India
[2] Yeungnam Univ, Coll Nat Sci, Dept Chem, 280 Daehak Ro, Gyongsan 38541, Gyeongbuk, South Korea
基金
新加坡国家研究基金会;
关键词
Hydrogenation; Furfural; Levulinic acid; Rice husk derived carbon-silica; Ni catalysts; GAMMA-VALEROLACTONE; MESOPOROUS SILICA; COPPER-CATALYSTS; ASH; ADSORPTION; ALCOHOL; HYDROCYCLIZATION; NANOPARTICLES; CONVERSION; STABILITY;
D O I
10.1016/j.fuel.2019.116339
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
To achieve good activity in a continuous vapor phase hydrogenation of biomass-derived molecules via levulunic acid and furfural over rice husk derived C-SiO2 supported nickel (5-30 wt% Ni loading catalysts), synthesized by wet impregnation method have been used for the first time. Among the catalysts, 15 wt% Ni/C-SiO2 catalyst exhibited good activity in both furfural and levulunic acid hydrogenations due to higher Ni dispersion and smaller particle size. The activity exhibited by 15 wt% Ni/C-SiO2 for both hydrogenation reactions is either superior or on par with the catalysts cited in the literature under similar reaction conditions.
引用
收藏
页数:10
相关论文
共 61 条
[1]   Sorption kinetics of copper, zinc, cadmium and nickel ions on synthesized silico-antimonate ion exchanger [J].
Abou-Mesalam, MM .
COLLOIDS AND SURFACES A-PHYSICOCHEMICAL AND ENGINEERING ASPECTS, 2003, 225 (1-3) :85-94
[2]   Catalytic conversion of biomass to biofuels [J].
Alonso, David Martin ;
Bond, Jesse Q. ;
Dumesic, James A. .
GREEN CHEMISTRY, 2010, 12 (09) :1493-1513
[3]   A study on the consecutive preparation of silica powders and active carbon from rice husk ash [J].
An, Dongmin ;
Guo, Yupeng ;
Zou, Bo ;
Zhu, Yanchao ;
Wang, Zichen .
BIOMASS & BIOENERGY, 2011, 35 (03) :1227-1234
[4]  
[Anonymous], 2011, BP Statistical Review of World Energy
[5]  
BAUER B, 1985, NEW YORK TIMES BK R, P1
[6]  
Begum PS, 2013, IJST, V2, P1027
[7]   Production of levulinic acid and use as a platform chemical for derived products [J].
Bozell, JJ ;
Moens, L ;
Elliott, DC ;
Wang, Y ;
Neuenscwander, GG ;
Fitzpatrick, SW ;
Bilski, RJ ;
Jarnefeld, JL .
RESOURCES CONSERVATION AND RECYCLING, 2000, 28 (3-4) :227-239
[8]   CHEMISTRY Connecting Biomass and Petroleum Processing with a Chemical Bridge [J].
Bozell, Joseph J. .
SCIENCE, 2010, 329 (5991) :522-523
[9]   Hydrogenation of CO2 over nickel catalysts on rice husk ash-alumina prepared by incipient wetness impregnation [J].
Chang, FW ;
Kuo, MS ;
Tsay, MT ;
Hsieh, MC .
APPLIED CATALYSIS A-GENERAL, 2003, 247 (02) :309-320
[10]   Preparation of Cr2O3-promoted copper catalysts on rice husk ash by incipient wetness impregnation [J].
Chang, FW ;
Kuo, WY ;
Yang, HC .
APPLIED CATALYSIS A-GENERAL, 2005, 288 (1-2) :53-61