Fe(salan)-catalyzed asymmetric oxidation of sulfides with hydrogen peroxide in water

被引：257

作者：

Egami, Hiromichi ^{[1
]}

Katsuki, Tsutomu ^{[1
]}

机构：

[1] Kyushu Univ, Fac Sci, Grad Sch, Dept Chem,Higashi Ku, Fukuoka 8128581, Japan

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 29期

关键词：

D O I：

10.1021/ja071916+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new chiral Fe(salan) complex was synthesized, and it was found to serve as an efficient catalyst for asymmetric oxidation of sulfides using hydrogen peroxide in water without surfactant. Not only alkyl aryl sulfides but also various methyl alkyl sulfides were oxidized to the corresponding sulfoxides with high enantioselectivities up to 96% ee. It should be noted that the turnover number of complex 4 amounts to 8000.

引用

页码：8940 / +

页数：3

共 50 条

[11] Asymmetric oxidation of sulfides with hydrogen peroxide catalyzed by a vanadium complex of a new chiral NOO-ligand [J].

Liu, Haibin ;

Wang, Mei ;

Wang, Yu ;

Wang, Ying ;

Sun, Hui ;

Sun, Licheng .

CATALYSIS COMMUNICATIONS, 2009, 11 (04) :294-297

[12] Asymmetric epoxidation of olefins catalyzed by Ti(salan) complexes using aqueous hydrogen peroxide as the oxidant [J].

Matsumoto, Kazuhiro ;

Sawada, Yuji ;

Katsuki, Tsutomu .

PURE AND APPLIED CHEMISTRY, 2008, 80 (05) :1071-1077

[13] Mechanism of bicarbonate-catalyzed oxidation of sulfides by hydrogen peroxide. [J].

Yao, HR ;

Bennett, D ;

Frank, K ;

Xu, C ;

Richardson, D .

ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 :U840-U840

[14] Titanium(IV)-Salan Catalysts for Asymmetric Sulfoxidation with Hydrogen Peroxide [J].

Adao, Pedro ;

Avecilla, Fernando ;

Bonchio, Marcella ;

Carraro, Mauro ;

Pessoa, Joao Costa ;

Correia, Isabel .

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2010, (35) :5568-5578

[15] Biphasic oxidation of sulfides with hydrogen peroxide, catalyzed by partially water-soluble cationic salphen complex [J].

Amir Abdolmaleki ;

Saeed Malek-Ahmadi .

Journal of the Iranian Chemical Society, 2012, 9 :1015-1019

[16] Biphasic oxidation of sulfides with hydrogen peroxide, catalyzed by partially water-soluble cationic salphen complex [J].

Abdolmaleki, Amir ;

Malek-Ahmadi, Saeed .

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY, 2012, 9 (06) :1015-1019

[17] ASYMMETRIC OXIDATION OF SULFIDES, CATALYZED BY CHLOROPEROXIDASE [J].

COLONNA, S ;

GAGGERO, N ;

MANFREDI, A ;

CASELLA, L ;

GULLOTTI, M .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1988, (22) :1451-1452

[18] HIGHLY ENANTIOSELECTIVE CATALYTIC ASYMMETRIC OXIDATION OF SULFIDES USING HYDROGEN-PEROXIDE [J].

PAGE, PCB ;

HEER, JP ;

BETHELL, D ;

COLLINGTON, EW ;

ANDREWS, DM .

SYNLETT, 1995, (07) :773-775

[19] Oxidation of sulfides in petroleum diesel fraction with hydrogen peroxide catalyzed by molybdenum compounds [J].

P. P. Samatov ;

U. M. Dzhemilev ;

A. Kh. Sharipov .

Petroleum Chemistry, 2006, 46 :439-441

[20] Oxidation of sulfides in petroleum diesel fraction with hydrogen peroxide catalyzed by molybdenum compounds [J].

Samatov, P. P. ;

Dzhemilev, U. M. ;

Sharipov, A. Kh. .

PETROLEUM CHEMISTRY, 2006, 46 (06) :439-441

← 1 2 3 4 5 →