Monomer diffusion rates in photopolymer material. Part II. High-frequency gratings and bulk diffusion

被引:28
作者
Close, C. E. [1 ]
Gleeson, M. R. [1 ]
Mooney, D. A. [2 ]
Sheridan, J. T. [1 ]
机构
[1] Univ Coll Dublin, Commun & Optoelect Res Ctr, SFI Strateg Res Ctr Solar Energy Convers, Sch Elect Elect & Commun Engn, Dublin 4, Ireland
[2] Univ Coll Dublin, Sch Chem & Bioproc Engn, Coll Engn Math & Phys Sci, Dublin 4, Ireland
基金
爱尔兰科学基金会;
关键词
POLYMER; WATER; MODEL; POLYACRYLAMIDE; IMPROVEMENT; LIGHT;
D O I
10.1364/JOSAB.28.000842
中图分类号
O43 [光学];
学科分类号
070207 ; 0803 ;
摘要
Photosensitive polymers are of practical importance, and mass transport within such materials plays a critical role in their behavior. Building on the work in Part I [J. Opt. Soc. Am. B doc. ID 136413 (posted 5 January 2011, in press)], the diffusion constants of a number of materials (i.e., acrylamide, polyacrylamide, water, propanol, and acetone) within a photosensitive layer are measured. A combination of optical and physical chemistry techniques is applied under different conditions. Determining the rates of diffusion is beneficial as it: (i) indicates material stability over time and (ii) supports material characterization, modeling, and performance optimization. (C) 2011 Optical Society of America
引用
收藏
页码:842 / 850
页数:9
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