New synthesis method for metal phosphide hydrotreating catalysts: MoP/SiO2 and MoP/Al2O3

被引：8

作者：

Yang, Shaofeng ^{[1
]}

Liang, Changhai ^{[1
]}

Prins, Roel ^{[1
]}

机构：

[1] ETH, Inst Chem & Bioengn, CH-8093 Zurich, Switzerland

来源：

SCIENTIFIC BASES FOR THE PREPARATION OF HETEROGENEOUS CATALYSTS, PROCEEDINGS OF THE 9TH INTERNATIONAL SYMPOSIUM | 2006年 / 162卷

关键词：

D O I：

10.1016/S0167-2991(06)80921-3

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

MoP/SiO(2) and MoP/Al(2)O(3) can be prepared by treating supported Mo metal particles with phosphine and hydrogen. The resulting materials have high activities in the hydrodesulfurization of dibenzothiophene and the hydrodenitrogenation of o-methylaniline.

引用

页码：307 / 314

页数：8

共 15 条

[1] Synthesis and activity of a new catalyst for hydroprocessing: Tungsten phosphide [J].

Clark, P ;

Li, W ;

Oyama, ST .

JOURNAL OF CATALYSIS, 2001, 200 (01) :140-147

[2] Alumina-supported molybdenum phosphide hydroprocessing catalysts [J].

Clark, PA ;

Oyama, ST .

JOURNAL OF CATALYSIS, 2003, 218 (01) :78-87

[3]

CORDERO RL, 1991, APPL CATAL, V74, P125

[4] Hydrodesulfurization of dibenzothiophene and 4,6-dimethyldibenzothiophene over sulfided NiMo/γ-Al2O3, CoMo/γ-Al2O3, and Mo/γ-Al2O3 catalysts [J].

Egorova, M ;

Prins, R .

JOURNAL OF CATALYSIS, 2004, 225 (02) :417-427

[5] Molybdenum phosphide: A novel catalyst for hydrodenitrogenation [J].

Li, W ;

Dhandapani, B ;

Oyama, ST .

CHEMISTRY LETTERS, 1998, (03) :207-208

[6] Structure of oxidic NiMo/SiO2 hydrotreating catalyst precursors [J].

Medici, L ;

Prins, R .

JOURNAL OF CATALYSIS, 1996, 163 (01) :28-37

[7] Novel catalysts for advanced hydroprocessing: transition metal phosphides [J].

Oyama, ST .

JOURNAL OF CATALYSIS, 2003, 216 (1-2) :343-352

[8] Synthesis, characterization, and hydrodesulfurization properties of silica-supported molybdenum phosphide catalysts [J].

Phillips, DC ;

Sawhill, SJ ;

Self, R ;

Bussell, ME .

JOURNAL OF CATALYSIS, 2002, 207 (02) :266-273

[9] Thiophene hydrodesulfurization over supported nickel phosphide catalysts [J].

Sawhill, SJ ;

Phillips, DC ;

Bussell, ME .

JOURNAL OF CATALYSIS, 2003, 215 (02) :208-219

[10] Preparation and 31P NMR characterization of nickel phosphides on silica [J].

Stinner, C ;

Tang, Z ;

Haouas, M ;

Weber, T ;

Prins, R .

JOURNAL OF CATALYSIS, 2002, 208 (02) :456-466

← 1 2 →