4-Substituted tert-Butyl Phenylazocarboxylates-Synthetic Equivalents for the para-Phenyl Radical Cation

被引：33

作者：

Hoefling, Sarah B. ^{[1
]}

Bartuschat, Amelie L. ^{[1
]}

Heinrich, Markus R. ^{[1
]}

机构：

[1] Univ Erlangen Nurnberg, D-91052 Erlangen, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 50期

关键词：

arenes; aromatic substitution; nucleophilic substitution; radical reactions; synthetic methods; NUCLEOPHILIC AROMATIC-SUBSTITUTION; FRAGMENTIERUNG VON AZOVERBINDUNGEN; SECONDARY-AMINES; DISPLACEMENT; PHENYLDIIMIDE; NITROBENZENES; TAUTOMERISM; HETEROLYSIS; CHEMISTRY; ARYLATION;

D O I：

10.1002/anie.201004508

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

First electrophile, then radical: 4-Substituted tert-butyl phenylazocarboxylates 1 are versatile synthetic equivalents of the para-phenyl radical cation 2. The tert-butyloxycarbonylazo group enables nucleophilic substitutions to proceed under mild conditions and can later be employed for the generation of aryl radicals. Copyright © 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：9769 / 9772

页数：4

共 71 条

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