1-(2-bromo-5-methoxybenzoyl)thiosemicarbazide

被引:2
作者
Sarojini, B. K.
Narayana, B.
Veena, K.
Yathirajan, H. S.
Bolte, Michael
机构
[1] Goethe Univ Frankfurt, Inst Anorgan Chem, D-60438 Frankfurt, Germany
[2] PA Coll Engn, Dept Chem, Mangalore 574153, India
[3] Mangalore Univ, Dept Studies Chem, Mangalagangothri 574199, India
[4] Univ Mysore, Dept Studies Chem, Mysore 570006, Karnataka, India
来源
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词
D O I
10.1107/S1600536807039803
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The geometric parameters of the title molecule, C9H10BrN3O2S, are in the usual ranges. The mean plane of the thiourea group is almost parallel to the plane of the benzene ring [ dihedral angle = 8.40 (12)degrees]. Only the torsion angles about the C-carbonyl - C-aromatic bond and the N-N bond differ significantly from 0 or 180 degrees. The crystal packing is stabilized by N-H center dot center dot center dot O and N-H center dot center dot center dot S hydrogen bonds.
引用
收藏
页码:O3844 / U3336
页数:9
相关论文
共 19 条
  • [1] AN EMPIRICAL CORRECTION FOR ABSORPTION ANISOTROPY
    BLESSING, RH
    [J]. ACTA CRYSTALLOGRAPHICA SECTION A, 1995, 51 : 33 - 38
  • [2] Theoretical study of the Hg2+ recognition by 1,3-diphenyl-thiourea
    Castro, M
    Cruz, J
    Otazo-Sánchez, E
    Perez-Marín, L
    [J]. JOURNAL OF PHYSICAL CHEMISTRY A, 2003, 107 (42) : 9000 - 9007
  • [3] STRUCTURE OF 4-(3-CHLOROPHENYL)THIOSEMICARBAZIDE
    CHATTOPADHYAY, D
    BANERJEE, T
    MAZUMDAR, SK
    GHOSH, S
    KURODA, R
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1991, 47 : 112 - 115
  • [4] STRUCTURE OF 4-(4-METHOXYPHENYL)THIOSEMICARBAZIDE
    CHATTOPADHYAY, D
    BANERJEE, T
    MAJUMDAR, SK
    GHOSH, S
    KURODA, R
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 974 - 977
  • [5] STRUCTURE OF 1-(3,4-DICHLOROPHENYL)-4-METHYLTHIOSEMICARBAZIDE
    CHATTOPADHYAY, D
    MAZUMDAR, SK
    BANERJEE, T
    SHELDRICK, WS
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1989, 45 : 314 - 317
  • [6] 1-(4-methylamino-1,2,5-thiadiazole-3-carbonyl)thiosemicarbazide
    Fonari, MS
    Simonov, YA
    Lipkowski, J
    Yavolovskii, AA
    [J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 2003, 59 : O491 - O493
  • [7] 4-Phenyl-1-(1-phenylethylidene)thiosemicarbazide
    Jian, FF
    Li, Y
    Xiao, HL
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2005, 61 : O2219 - O2220
  • [8] Solid-phase synthesis of 2-aminothiazoles
    Kearney, PC
    Fernandez, M
    Flygare, JA
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1998, 63 (01) : 196 - 200
  • [9] Development of N-benzamidothioureas as a new generation of thiourea-based receptors for anion recognition and sensing
    Nie, L
    Li, Z
    Han, J
    Zhang, X
    Yang, R
    Liu, WX
    Wu, FY
    Xie, JW
    Zhao, YF
    Jiang, YB
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 2004, 69 (19) : 6449 - 6454
  • [10] Comparative cytotoxicity of N-substituted N′-(4-imidazole-ethyl)thiourea in precision-cut rat liver slices
    Onderwater, RCA
    Commandeur, JNM
    Vermeulen, NPE
    [J]. TOXICOLOGY, 2004, 197 (02) : 81 - 91