Multiple-objective optimization in green fuel production via catalytic deoxygenation reaction with NiO-dolomite catalyst

This study investigates the multi-objective optimization of reaction parameters with response surface method-ology (RSM) with central composite design (CCD) for the deoxygenation of waste cooking oil (WCO) over low cost-modified local carbonate mineral catalyst (NiO-Malaysian dolomite) into green fuel in the range of gasoline, kerosene and diesel. RSM was performed to study the effect of four operating parameters: temperature (390-430 degrees C), time (30-120 min), catalyst loading (1-10 wt%) and nitrogen flow rate (50-300 cm(3)/min). The results indicate that for maximum WCO conversion, deoxygenated oil and product yield, the optimum param-eters of the deoxygenation reaction were at 410 degrees C, 60 min, 5.50 wt% of catalyst loading, and 175 cm(3)/min of N-2. The green fuel properties testing (density, kinematic viscosity, flash point, cloud point, pour point, sulfur, carbon residue, cetane index, oxidation stability, acid value, iodine value and calorific value) and GC-MS analysis show that the product oil meets almost all the requirements of green diesel fuel and hydrocarbon biofuel standards for fuel application while the quadratic model proposed agreed with the experimental data (95% confidence) which indicates that the RSM can adequately predict the reaction products.