Dipole Polarization Formed on Surface of Polypropylene Electrets

被引：11

作者：

Matsuda, Yasuhiro ^{[1
]}

Saito, Yoshihiro ^{[1
]}

Tasaka, Shigeru ^{[1
]}

机构：

[1] Shizuoka Univ, Dept Mat Sci & Chem Engn, Naka Ku, Hamamatsu, Shizuoka 4328561, Japan

来源：

IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION | 2010年 / 17卷 / 04期

关键词：

Electrets; polypropylene films; surface treatment; dipole arrays; corona; FILMS;

D O I：

10.1109/TDEI.2010.5539669

中图分类号：

TM [电工技术]; TN [电子技术、通信技术];

学科分类号：

0808 ; 0809 ;

摘要：

The surface chemical composition and pyroelectric properties in polypropylene (PP) film poled by corona discharge in the air were estimated by Fourier transform infrared spectrophotometry (FTIR), gel permeation chromatography (GPC), differential scanning calorimetry (DSC), thermally stimulated depolarization current (TSDC), and pyroelectricity measurement. The corona discharge oxidized the PP chains at the surface into oligomers bearing C=O, C-O and COH groups, and formed hetero charge, and counter homo charge absorbed strongly on the surface. The pyroelectricity and surface potential were undetected after removing the polymer surface with solvent or scratching. TSDC curves indicated that the both homo and hetero charges were stable below the melting point of the oligomers. The stabilization mechanism of surface potential was investigated from the electric behavior and the chemical structure of poled PP films.

引用

页码：1015 / 1020

页数：6

共 12 条

[1] ELECTRICAL-DISCHARGE TREATMENT OF POLYPROPYLENE FILM
BRIGGS, D
KENDALL, CR
BLYTHE, AR
WOOTTON, AB
[J]. POLYMER, 1983, 24 (01) : 47 - 52
[2] POLARIZATION OF ELECTRET
GROSS, B
MORAES, RJ
[J]. JOURNAL OF CHEMICAL PHYSICS, 1962, 37 (04) : 710 - &
[3] ON PERMANENT CHARGES IN SOLID DIELECTRICS .1. DIELECTRIC ABSORPTION AND TEMPERATURE EFFECTS IN CARNAUBA WAX
GROSS, B
DENARD, LF
[J]. PHYSICAL REVIEW, 1945, 67 (7-8): : 253 - 259
[4] ON PERMANENT CHARGES IN SOLID DIELECTRICS .2. SURFACE CHARGES AND TRANSIENT CURRENTS IN CARNAUBA WAX
GROSS, B
[J]. JOURNAL OF CHEMICAL PHYSICS, 1949, 17 (10) : 866 - 872
[5] Electret properties of polypropylene fabrics
Lowkis, B
Motyl, E
[J]. JOURNAL OF ELECTROSTATICS, 2001, 51 (1-4) : 232 - 238
[6] DIRECT MEASUREMENT OF THE SURFACE-ENERGY OF CORONA-TREATED POLYETHYLENE USING THE SURFACE FORCES APPARATUS
MANGIPUDI, V
TIRRELL, M
POCIUS, AV
[J]. LANGMUIR, 1995, 11 (01) : 19 - 23
[7] Charging characteristics for electret filter materials
Nifuku, M
Zhou, Y
Kisiel, A
Kobayashi, T
Katoh, H
[J]. JOURNAL OF ELECTROSTATICS, 2001, 51 (1-4) : 200 - 205
[8] Sellin Noeli, 2003, Mat. Res., V6, P163
[9] Sessler GM, 1999, BRAZ J PHYS, V29, P233
[10] Electret properties and chemical modification of cellular polypropylene films
Tang, Minmin
An, Zhenlian
Xia, Zhongfu
Zhang, Xiaoqing
[J]. JOURNAL OF ELECTROSTATICS, 2007, 65 (04) : 203 - 208

← 1 2 →