Zinc Coordination Complex for use in Uniform ZnS Microflowers Synthesis

被引:1
作者
Mi, Liwei [1 ]
Han, Minle [3 ]
Li, Zhen [2 ]
Yang, Fengling [2 ]
Shen, Changyu [1 ]
Zheng, Zhi [2 ]
机构
[1] Zhengzhou Univ, Natl Engn & Res Ctr Adv Polymer Proc Technol, Zhengzhou 450001, Henan, Peoples R China
[2] Xuchang Univ, Inst Surface Micro & Nano Mat, Xuchang 461000, Peoples R China
[3] Luoyang Normal Univ, Dept Chem, Luoyang 471022, Peoples R China
来源
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2010年 / 636卷 / 11期
基金
中国博士后科学基金; 美国国家科学基金会;
关键词
Zinc; Thiourea; Nanostructures; Coordination compounds; ZnS microflowers; NANOSTRUCTURES; PHASE; NANOPARTICLES; NANOCRYSTALS; NANOSPHERES; TEMPERATURE; TRANSITION; MORPHOLOGY; SPHERES;
D O I
10.1002/zaac.201000136
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Uniform snowball zinc sulfide (ZnS) microflowers with nanosheet covering were synthesized using the one step reaction of zinc coordination compounds with thiourea at 160 C for 24 h. X-ray single crystal diffraction, electron microscopy, energy-dispersive X-ray spectrometry, and X-ray diffraction were used to characterize the products. The flower-like ZnS crystals may have some application in catalyst or solar cell devices. This work is also expected to be applied in the fabrication of other transition metal sulfide crystals with special morphology.
引用
收藏
页码:1913 / 1916
页数:4
相关论文
共 23 条
[1]   Semiconductor clusters, nanocrystals, and quantum dots [J].
Alivisatos, AP .
SCIENCE, 1996, 271 (5251) :933-937
[2]   Synthesis of CdS and ZnS nanowires using single-source molecular precursors [J].
Barrelet, CJ ;
Wu, Y ;
Bell, DC ;
Lieber, CM .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (38) :11498-11499
[3]  
*CAMBR CRYST DAT C, 767807 CCDC
[4]   Synthesis of wurtzite ZnS nanowire bundles using a solvothermal technique [J].
Chai, Lanlan ;
Du, Jin ;
Xiong, Shenglin ;
Li, Haibo ;
Zhu, Yongchun ;
Qian, Yitai .
JOURNAL OF PHYSICAL CHEMISTRY C, 2007, 111 (34) :12658-12662
[5]   ZnO-Templated Synthesis of Wurtzite-Type ZnS and ZnSe Nanoparticles [J].
Dawood, Farah ;
Schaak, Raymond E. .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2009, 131 (02) :424-+
[6]   Inorganic semiconductor nanostructures and their field-emission applications [J].
Fang, Xiaosheng ;
Bando, Yoshio ;
Gautam, Ujjal K. ;
Ye, Changhui ;
Golberg, Dmitri .
JOURNAL OF MATERIALS CHEMISTRY, 2008, 18 (05) :509-522
[7]   Mass production and high photocatalytic activity of ZnS nanoporous nanoparticles [J].
Hu, JS ;
Ren, LL ;
Guo, YG ;
Liang, HP ;
Cao, AM ;
Wan, LJ ;
Bai, CL .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (08) :1269-1273
[8]   Phase evolution and morphology control of ZnS in a solvothermal system with a single precursor [J].
Jiang, Linfeng ;
Yang, Ming ;
Zhu, Shiyao ;
Pang, Guangsheng ;
Feng, Shouhua .
JOURNAL OF PHYSICAL CHEMISTRY C, 2008, 112 (39) :15281-15284
[9]   Syntheses, structures, and photoluminescence of a series of silver(I) sulfonates with pyrazine derivatives [J].
Liu, Hai-Yan ;
Wu, Hua ;
Ma, Jian-Fang ;
Yang, Jin ;
Liu, Ying-Ying .
DALTON TRANSACTIONS, 2009, (38) :7957-7968
[10]   Facile synthesis of hollow ZnS nanospheres in block copolymer solutions [J].
Ma, YR ;
Qi, LM ;
Ma, JM ;
Cheng, HM .
LANGMUIR, 2003, 19 (09) :4040-4042