First intermolecular hydroacylation of 1,3-dienes with aldehydes catalyzed by ruthenium

被引：77
|
作者：
Kondo, T [1 ]
Hiraishi, N [1 ]
Morisaki, Y [1 ]
Wada, K [1 ]
Watanabe, Y [1 ]
Mitsudo, T [1 ]
机构：
[1] Kyoto Univ, Grad Sch Engn, Dept Energy & Hydrocarbon Chem, Sakyo Ku, Kyoto 6068501, Japan
来源：
ORGANOMETALLICS | 1998年 / 17卷 / 10期
关键词：
D O I：
10.1021/om971084w
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Ru(cod)(cot)-PPh3 (cod = 1,5-cyclooctadiene, cot = 1,3,5-cyclooctatriene) is an effective catalyst system for the intermolecular hydroacylation of 1,3-dienes with aromatic and heteroaromatic aldehydes to give the corresponding beta,gamma-unsaturated ketones in reasonable yields. In this reaction, carbon monoxide is not needed to suppress decarbonylation of aldehydes. The key intermediate is an (acyl)(eta(3)-allyl)ruthenium complex which undergoes reductive elimination to give the corresponding ketones.
引用
收藏
页码：2131 / 2134
页数：4
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