Rational design of a chiral palladium(0) olefin complex of unprecedented stability

被引：43

作者：

Grundl, MA ^{[1
]}

Kennedy-Smith, JJ ^{[1
]}

Trauner, D ^{[1
]}

机构：

[1] Univ Calif Berkeley, Dept Chem, Ctr New Direct Organ Synth, Berkeley, CA 94720 USA

来源：

ORGANOMETALLICS | 2005年 / 24卷 / 12期

关键词：

D O I：

10.1021/om050277d

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A chiral bidentate olefin ligand L with a 1,4a,5,8a-tetrahydro-naphthalene-2,6-dione framework has been designed, which forms a homoleptic palladium(0) complex L2Pd of unprecedented stability.

引用

页码：2831 / 2833

页数：3

共 41 条

[11] ORTEP-3 for Windows - a version of ORTEP-III with a Graphical User Interface (GUI) [J].

Journal of Applied Crystallography, 1997, 30 (pt 5)

[12] Readily available [2.2.2]-bicyclooctadienes as new chiral ligands for Ir(I): Catalytic, kinetic resolution of allyl carbonates [J].

Fischer, C ;

Defieber, C ;

Suzuki, T ;

Carreira, EM .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2004, 126 (06) :1628-1629

[13] NICKEL(0)-CARBENE COMPLEXES [J].

GABOR, B ;

KRUGER, C ;

MARCZINKE, B ;

MYNOTT, R ;

WILKE, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (12) :1666-1668

[14] Chiral olefin Ligands - New "Spectators" in asymmetric catalysis [J].

Glorius, F .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2004, 43 (26) :3364-3366

[15] IRIDIUM ALKOXIDE AND AMIDE HYDRIDE COMPLEXES - SYNTHESIS, REACTIVITY, AND THE MECHANISM OF O-H AND N-H REDUCTIVE ELIMINATION [J].

GLUECK, DS ;

WINSLOW, LJN ;

BERGMAN, RG .

ORGANOMETALLICS, 1991, 10 (05) :1462-1479

[16] SYNTHESES OF PALLADIUM(0) AND PLATINUM(0) OLEFIN COMPLEXES - MOLECULAR-STRUCTURES OF [PT(C2F4)(C2H4)2] AND TRIS(BICYCLO[2.2.1]HEPTENE) PLATINUM [J].

GREEN, M ;

HOWARD, JAK ;

SPENCER, JL ;

STONE, GA .

JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1975, (11) :449-451

[17] Preparation of enantiomerically pure 5-palladatricyclo[4.1.0.0(2,4)]heptanes and conversion into enantiomerically pure complexes with helical chirality at palladium [J].

Hashmi, ASK ;

Naumann, F ;

Probst, R ;

Bats, JW .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1997, 36 (1-2) :104-106

[18] 1,6-diene complexes of palladium(0) and platinum(0):: Highly reactive sources for the naked metals and [L-M0] fragments [J].

Krause, J ;

Cestaric, G ;

Haack, KJ ;

Seevogel, K ;

Storm, W ;

Pörschke, KR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1999, 121 (42) :9807-9823

[19] REACTIONS OF ORGANOAZIDES WITH NICKEL ALKYLS - SYNTHESES AND REACTIONS OF NICKEL(II) AMIDO COMPLEXES [J].

MATSUNAGA, PT ;

HESS, CR ;

HILLHOUSE, GL .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1994, 116 (08) :3665-3666

[20] PALLADIACYCLOPENTADIENE AND PLATINIACYCLOPENTADIENE COMPLEXES AS INTERMEDIATES IN PD0 AND PT0 CATALYSED ACETYLENE CYCLOTRIMERIZATION REACTIONS [J].

MOSELEY, K ;

MAITLIS, PM .

JOURNAL OF THE CHEMICAL SOCIETY D-CHEMICAL COMMUNICATIONS, 1971, (24) :1604-&

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