A PSS-Free PEDOT Conductive Film Supported by a Hierarchical Nanoporous Layer Glass

被引：12

作者：

Fujima, Takuya ^{[1
]}

Uchiyama, Kentaro ^{[1
]}

Yasumoro, Keita ^{[1
]}

Ito, Takumi ^{[1
]}

Tabata, Erika ^{[1
]}

机构：

[1] Tokyo City Univ, Dept Mech Engn, Setagaya Ku, 1-28-1 Tamazutsumi, Tokyo 1588557, Japan

来源：

MACROMOLECULAR MATERIALS AND ENGINEERING | 2018年 / 303卷 / 09期

关键词：

PEDOT; porous materials; PSS-free; stabilizer-free; transparent conductive films; VAPOR-PHASE POLYMERIZATION; THIN-FILMS; TRANSPARENT; ELECTRODES; DEVICES; WATER;

D O I：

10.1002/mame.201800183

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

The importance of transparent conductive film is increasing due to its use in applications such as touch-panel devices. Although indium tin oxide is widely used because of its high conductivity and transparency, conductive polymers are being studied as alternative materials that avoid the use of rare metals and the brittleness associated with existing systems. Polyethylene dioxythiophene (PEDOT)/polyethylene sulfonic acid (PSS) is drawing a lot of attention due to its well-balanced conductivity, transparency, film formability, and chemical stability. The nonconductive PSS reportedly covers the conductive PEDOT. The PSS shell provides carrier and film-formability to PEDOT but is also a barrier that hinders electrical conductivity. Therefore, the PEDOT film formability is explored supported by a substrate without the addition of PSS. The hierarchical nanoporous layer glass holds the PSS-free PEDOT with its nanopores to form a homogeneous, transparent film. The PSS-free PEDOT film thus achieves transparency of over 85% and resistivity of below 500 sq(-1).

引用

页数：4

共 28 条

[1] Single-Crystal Poly(3,4-ethylenedioxythiophene) Nanowires with Ultrahigh Conductivity [J].