Monitoring the radiation-induced bulk polymerisation of methyl methacrylate with N-(1-pyrene)maleimide

被引：11
|
作者：
Frahn, MS [1 ]
Warman, JM [1 ]
Abellon, RD [1 ]
Luthjens, LH [1 ]
机构：
[1] Delft Univ Technol, Interfac Reactor Inst, Radiat Chem Dept, NL-2629 JB Delft, Netherlands
来源：
RADIATION PHYSICS AND CHEMISTRY | 2001年 / 60卷 / 4-5期
关键词：
fluorogenic probe; radiation; methyl methacrylate; PMMA; polymerisation;
D O I：
10.1016/S0969-806X(00)00420-5
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The fluorogenic probe N-(1-pyrene)maleimide, MPy, exhibits a fluorescence response directly correlated to the monomer conversion in the radiation-induced polymerisation of methyl methacrylate (MMA). In the low-dose region, the ratio between propagation rate constants for the cross-over reaction in which a MMA radical chain-end reacts with MPy relative to the homopolymerisation reaction of MMA is found to be 1.38 +/- 0.15. (C) 2001 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：433 / 437
页数：5
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