Enantioselective oxidative boron Heck reactions

被引：65

作者：

Lee, A. -L. ^{[1
]}

机构：

[1] Heriot Watt Univ, Sch Engn & Phys Sci, Inst Chem Sci, Edinburgh EH14 4AS, Midlothian, Scotland

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2016年 / 14卷 / 24期

基金：

英国工程与自然科学研究理事会;

关键词：

ASYMMETRIC CONJUGATE ADDITION; REGIOSELECTIVE DIRECT ARYLATION; ARYLBORONIC ACIDS; BASE-FREE; STEREOSELECTIVE-SYNTHESIS; ALKENYL ALCOHOLS; CYCLIC ENONES; ACYCLIC ALKENES; ARYL; CATALYSIS;

D O I：

10.1039/c5ob01984b

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

This review highlights the use of the oxidative boron Heck reaction in enantioselective Heck-type couplings. The enantioselective oxidative boron Heck reaction overcomes several limitations of the traditional Pd(0)-catalysed Heck coupling and has subsequently allowed for intermolecular couplings of challenging systems such as cyclic enones, acyclic alkenes, and even site selectively on remote alkenes.

引用

页码：5357 / 5366

页数：10

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