The magnetic properties of strontium hexaferrites with La-Cu substitution prepared by SHS method

被引:94
作者
Qiao, Liang [1 ]
You, Lishun [1 ]
Zheng, Jingwu [1 ]
Jiang, Liqiang [1 ]
Sheng, Jiawei [1 ]
机构
[1] Zhejiang Univ Technol, Coll Chem Engn & Mat Sci, Hangzhou 310014, Peoples R China
关键词
SHS; ferrite; substitute; magnetic property;
D O I
10.1016/j.jmmm.2007.04.028
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
La-Cu substituted strontium hexaferrites with the chemical composition of Sr1-xLaxFe12-xCuxO19 were prepared by self-propagating high-temperature synthesis. The effects of La-Cu substitution on the microstructure and magnetic properties of Sr-ferrites were studied. The XRD results show that all the samples are single SrM-type phase for x<0.4. Compared with the samples without La-Cu substitution, the magnetic properties of the samples with the composition of Sr1-xLaxFe12-xCuxO19 are remarkably improved for x<0.4. The possibility that the substitution of Sr2+ by La3+ in the Sr-layer makes the Cu2+ preferably substitutes the Fe3+ in 4f(2) sites is predicted to be associated with the improvement of the magnetic properties of La-Cu substituted samples. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码:74 / 78
页数:5
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