Vibrational dephasing mechanisms in hydrogen-bonded systems

被引：29

作者：

Bonn, M ^{[1
]}

Brugmans, MJP ^{[1
]}

Kleyn, AW ^{[1
]}

vanSanten, RA ^{[1
]}

Bakker, HJ ^{[1
]}

机构：

[1] EINDHOVEN UNIV TECHNOL,SCHUIT INST CATALYSIS,5600 MB EINDHOVEN,NETHERLANDS

来源：

PHYSICAL REVIEW LETTERS | 1996年 / 76卷 / 14期

关键词：

D O I：

10.1103/PhysRevLett.76.2440

中图分类号：

O4 [物理学];

学科分类号：

0702 ;

摘要：

With transient IR hole-burning spectroscopy we observe large variations in the homogeneous linewidth 1 of the nu(s)(O-D) stretch vibration of differently hydrogen-bonded surface hydroxyls in zeolite catalysts. The linewidth is very sensitive to the frequency of the nu(sigma)(OD ... X) hydrogen-bond vibration. By varying this frequency we obtain conclusive information on the coupling between the nu(s)(O-D) and the nu(sigma)(OD ... X) modes.

引用

页码：2440 / 2443

页数：4

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